1973年出生。1996年7月本科毕业于合肥工业大学。1999年7月获得中国科学技术大学高分子化学与物理硕士学位,导师为何平笙教授和阮德礼教授。2005年3月获Virginia Polytechnic Institute & State University有机与高分子化学博士学位,导师为Harry W. Gibson教授。后在University of Utah化学系从事博士后工作,导师为Peter J. Stang教授。2005年12月起任浙江大学化学系教授,筹建超分子化学研究小组。2008年3月起任浙江大学求是特聘教授。2018年5月起任浙江大学长江学者特聘教授。主要从事超分子化学方面的研究工作,当前的主要研究兴趣包括超分子聚合物、超分子两亲分子、柱芳烃超分子化学、以及非多孔自适应晶体(简称:纳客;英文全称:nonporous adaptive crystals;英文简称:NACs)、纳米碳。已发表超分子化学相关论文458篇,包括1篇Nature、2篇Nature Chemistry、1篇Nature Materials、1篇Nature Synthesis、1篇Nature Review Chemistry、3篇PNAS、67篇Journal of the American Chemical Society、31篇Angewandte Chemie International Edition、16篇Advanced Materials、1篇Chem、和9篇Nature Communications。发表的论文已被引用46673次,H-index为121。两篇通讯作者论文入选“中国百篇最具影响国际学术论文”。2015年至今连年入选科睿唯安全球“高被引科学家”。到目前为止获得的主要奖励和荣誉有:2004年获国家优秀自费留学生奖学金和Virginia Polytechnic Institute & State University 优秀硕士论文William Preston 奖(William Preston Award for MS thesis),2005年获The Sigma Xi Society Research Award,2006年获Virginia Polytechnic Institute & State University优秀博士论文奖(Outstanding Dissertation Award),2006年入选浙江省“钱江人才计划”, 2007年获美国李氏基金会杰出成就奖并入选浙江省“新世纪151人才工程”,2008年被评选为浙江大学“十佳青年岗位能手”,2009年获Thieme Chemistry Journals Award并入选教育部 “新世纪优秀人才支持计划”,2010年获浙江省杰出青年科学基金项目资助和Virginia Polytechnic Institute & State University的 the Outstanding Recent Graduate Alumnus Award,2011年获国家杰出青年科学基金项目资助,指导博士生获得2011年全国百篇优秀博士论文提名奖,2012年入选英国皇家化学会会士(Fellow of the Royal Society of Chemistry, FRSC),2013年入选国家创新人才推进计划中青年科技创新领军人才,2013年入选亚洲化学大会Asian Rising Star,2013年获得浙江省青年科技奖,2014年获中国化学会-阿克苏诺贝尔化学奖,2015年获英国皇家化学会Cram Lehn Pedersen Prize in Supramolecular Chemistry,2016年获英国皇家化学会Polymer Chemistry Lectureship Award,2016年入选国家万人计划领军人才,2017年入选教育部长江学者奖励计划特聘教授,2018年获英国皇家学会Newton Advanced Fellowship,2019年获德国Bruno Werdelmann Lectureship Award,2019年获“浙江大学第六届师德先进个人”荣誉称号,2020年获教育部基础学科拔尖学生培养计划优秀导师奖,2020年入选浙江大学竺可桢学院年度最佳专业导师,2020年获浙江省自然科学奖一等奖(第一完成人),2023年入选中国化学会会士,2023年入选国务院政府特殊津贴专家。指导的博士生2015年(颜徐州)、2017年(揭克诚)、2021年(李二锐)、2024年(吴奕韬)、2025年(陈丽雅)五次获浙江大学优秀博士学位论文奖,四次(颜徐州、喻国灿、吉晓帆、周炯)获浙江大学竺可桢奖学金(每年最多十二名研究生可获该奖项),一次(吴奕韬,2024)获国家博新计划资助。应邀在国内外作学术报告240次,包括应邀到澳大利亚全国高分子会议上作学术报告,应邀在全国有机化学学术讨论会上作大会报告,应邀到第15届亚洲化学大会上作Asian Rising Stars分会邀请报告,应邀到韩国全国高分子会议上作学术报告,应邀在全国大环化学暨超分子化学学术讨论会上作大会报告,应邀在美国举行的第一届人工分子开关与马达高登会议(Gordon Research Conference)上作邀请报告,应邀在法国举行的第十届大环与超分子化学国际研讨会(ISMSC-10)上作大会报告,应邀在澳大利亚举行的第23届IUPAC国际物理有机化学会议上作大会报告,应邀在葡萄牙里斯本举行的第一届非共价相互作用国际会议上作大会报告,在英国考文垂举行的第50届IUPAC世界高分子大会上作大会报告。应邀担任Chemical Society Reviews、Accounts of Chemical Research、Chemical Reviews、Chemical Communications、Advanced Materials、和Materials Chemistry Frontiers的客座编辑。应邀担任Journal of the American Chemical Society(2020年起)、Chemical Society Reviews(2012年起)、Chemical Communications(2012年起)、化学学报(2012年-2018年)、Macromolecules (2014年-2017年)、ACS Macro Letters(2014年-2017年)、Polymer Chemistry(2014年起)、Materials Chemistry Frontiers(2016年起)、高分子学报(2016年起)、中国化学快报(2018年起)、Giant(2020年起)、Aggregate(2021年起)、Coordination Chemistry Reviews(2024年起)等的顾问编委或编委。现任国务院学位委员会化学学科评议组成员(2020年11月起)、中国化学会高分子学科委员会委员、中国化学会超分子化学专业委员会副主任委员、中国化学会晶体化学专业委员会委员、中国化学会分子聚集发光专业委员会委员、中国化学会分子医学专业委员会委员、中国化学会奖励推荐委员会委员、国际大环及超分子化学大会(ISMSC)国际科学委员会委员(2022年-2027年)、非共价相互作用国际会议国际顾问委员会委员(2019年起)、浙江省化学会理事、浙江大学新物质创制会聚研究计划(简称“天工计划”)首席科学家(2020年4月起)、浙江大学杭州国际科创中心超分子新物质创制创新工坊执行院长(2021年6月起)、九三学社浙江大学委员会副主委(2019年7月起)、九三学社浙江省委常委(2022年5月起)、九三学社浙江省委科技专门委员会主任(2022年9月起)、浙江-以色列自组装功能材料联合实验室主任(2022年12月起)、浙江省政协委员(2023年1月起)、浙江大学欧美同学会(留学人员联谊会)副会长(2023年1月起)、浙江大学杭州国际科创中心-杭州之江有机硅化工有限公司联合实验室主任(2023年1月起)、浙江省留学人员和家属联谊会副会长(2025年1月起)。
教学工作
高分子化学、超分子化学、化学选论
研究领域:超分子化学、超分子聚合物、主客体化学、超分子两亲分子、非多孔自适应晶体(NACs)、环状共轭分子。
具体方向:储能电池材料、工业催化、编织聚合物的构筑、框架材料、密封胶与粘接剂、化工分离、分子捕手、纳客。
工作研究项目
1. 基于分子尺度的运动构建具有宏观响应性的高分子,国家自然科学基金重点项目,22035006,起于2021年1月止于2025年12月,直接经费总额294万 (总经费352.8万),项目负责人。
2. 可应用于高附加值化学品转化的超分子智能分离材料的构筑,国家自然科学基金重点国际(地区)合作研究项目,22320102001,起于2024年1月止于2028年12月,直接经费216万 (总经费280.8万),项目负责人。
3. 主客体机械互锁结构增韧的环氧树脂,国家自然科学基金指南引导类原创探索计划项目,22350007,起于2024年1月止于2026年12月,直接经费300万 (总经费390万),项目负责人。
发表论文
1. Yuan, J.; Zuo, G.; Zuo, X.; Huang, F. Modification of Organic Glass and Its Progress. New Chemical Materials, 1996, 2-18.
2. Yuan, J.; Zuo, G.; Zuo, X.; Huang, F. Study on Surface Hardness of Organic Glass Prepared by Crosslinking Copolymerization. Modern Plastic Processing and Applications, 1997, 9, 15-17.
3. Yuan, J.; Zuo, G.; Zuo, X.; Huang, F. Study on Preparation and Properties of Copolymerized Crosslinked Organic Glass. Polymeric Materials Science and Engineering, 1999, 15, 154-156.
4. Zhang, Y.;* Huang, F.; Yuan, D. Study of Relationship of Structure and Properties of Photosensitive Prepolymer. Journal of China University of Science and Technology, 2000, 30, 201-207.
5. Huang, F.; Li, C.; He, P.* Cure Behavior of Interpenetrating Polymer Networks Studied by Dynamic Torsional Vibration Method. Polymeric Materials Science and Engineering, 2001, 17, 93-97.
6. Huang, F.; Fronczek, F. R.; Gibson, H. W.* First Supramolecular Poly(taco complex). Chem. Commun. 2003, 1480-1481.
7. Huang, F.; Fronczek, F. R.; Gibson, H. W.* A Cryptand/Bisparaquat [3]Pseudorotaxane by Cooperative Complexation. J. Am. Chem. Soc. 2003, 125, 9272-9273.
8. Huang, F.; Gibson, H. W.;* Bryant, W. S.; Nagvekar, D. S.; Fronczek, F. R. First Pseudorotaxane-Like [3]Complexes Based on Cryptands and Paraquat: Self-Assembly and Crystal Structures. J. Am. Chem. Soc. 2003, 125, 9367-9371.
9. Huang, F.; Zakharov, L. N.; Rheingold, A. L.; Jones, J. W.; Gibson, H. W.* Water Assisted Formation of a Pseudorotaxane and Its Dimer Based on a Supramolecular Cryptand. Chem. Commun. 2003, 2122-2123.
10. Gibson, H. W.;* Ge, Z. Huang, F.; Jones, J. W.; Wang, H.; Farcas, A. Mechanically Interlocked Macromolecular Systems via Pseudorotaxane Self-assembly. Polymer Preprints 2003, 44, 475-476.
11. Huang, F.; Jones, J. W.; Slebodnick, C.; Gibson, H. W.* Ion Pairing in Fast-Exchange Host-Guest Systems: Concentration Dependence of Apparent Association Constants for Complexes of Neutral Hosts and Divalent Guest Salts with Monovalent Counterions. J. Am. Chem. Soc. 2003, 125, 14458-14464.
12. Jones, J. W.; Huang, F.; Bryant, W. S.; Gibson, H. W.* A Cautionary Note Regarding the Investigation of Supramolecular Complexes Involving Secondary Ammonium Salts in Acetone. Tetrahedron Lett. 2004, 45, 5961-5963.
13. Huang, F.; Gibson, H. W.* Formation of a Supramolecular Hyperbranched Polymer from Self-Organization of an AB2 Monomer Containing a Crown Ether and Two Paraquat Moieties. J. Am. Chem. Soc. 2004, 126, 14738-14739.
14. Huang, F.; Zhou, L.; Jones, J. W.; Gibson, H. W.;* Ashraf-Khorassani, M. Formation of Dimers of Inclusion Cryptand/Paraquat Complexes Driven by Dipole-Dipole and Face-to-Face p-Stacking Interactions. Chem. Commun. 2004, 2670-2671.
15. Huang, F.; Nagvekar, D. S.; Slebodnick, C.; Gibson, H. W.* A Supramolecular Triarm Star Polymer from a Homotritopic Tris(Crown Ether) Host and a Complementary Monotopic Paraquat-Terminated Polystyrene Guest by a Supramolecular Coupling Method. J. Am. Chem. Soc. 2005, 127, 484-485.
16. Huang, F.; Zakharov, L. N.; Rheingold, A. L.; Ashraf-Khorassani, M.; Gibson, H. W.* Synthesis of a Symmetric Cylindrical Bis(crown ether) Host and Its Complexation with Paraquat. J. Org. Chem. 2005, 70, 809-813.
17. Gibson, H. W.;* Ge, Z.; Huang, F.; Jones, J. W.; Lefebvre, H.; Vergne, M. J.; Hercules, D. M. Syntheses and Model Complexation Studies of Well-Defined Crown Terminated Polymers. Macromolecules 2005, 38, 2626-2637.
18. Huang, F.; Guzei, I. A.; Jones, J. W.; Gibson, H. W.* Remarkably Improved Complexation of a Bisparaquat by Formation of a Pseudocryptand-Based [3]Pseudorotaxane. Chem. Commun. 2005, 1693-1695.
19. Huang, F.; Gibson, H. W.* A Supramolecular Poly[3]pseudorotaxane from Self-Assembly of a Homoditopic Cylindrical Bis(crown ether) Host and a Bisparaquat Derivative. Chem. Commun. 2005, 1696-1698.
20. Huang, F.; Switek, K. A.; Zakharov, L. N.; Fronczek, F. R.; Slebodnick, C.; Lam, M.; Golen, J. A.; Bryant, W. S.; Mason, P.; Rheingold, A. L.; Ashraf-Khorassani, M.; Gibson, H. W.* Bis(m-phenylene)-32-crown-10-Based Cryptands, Powerful Hosts for Paraquat Derivatives. J. Org. Chem. 2005, 70, 3231-3241.
21. Huang, F.; Lam, M.; Mahan, E. J.; Rheingold, A. L.; Gibson, H. W.* Promotion of Host Folding during the Formation of a Taco Complex. Chem. Commun. 2005, 3268-3270.
22. Huang, F.; Switek, K. A.; Gibson, H. W.* pH-Controlled Assembly and Disassembly of a Cryptand/Paraquat [2]Pseudorotaxane. Chem. Commun. 2005, 3655-3657.
23. Huang, F.; Gibson, H. W.* Polypseudorotaxanes and Polyrotaxanes. Prog. Polym. Sci. 2005, 30, 982-1018.
24. Huang, F.; Slebodnick, C.; Ratliff, A.; Gibson, H. W.* A Bis(m-phenylene)-32-crown-10/Monopyridinium [2]Pseudorotaxane. Tetrahedron Lett. 2005, 46, 6019-6022.
25. Huang, F.; Fronczek, F. R.; Ashraf-Khorassani, M.; Gibson, H. W.* Slow-Exchange C3-Symmetric Cryptand/Trispyridinium Inclusion Complexes Containing Nonlinear Guests: A New Type of Threaded Structure. Tetrahedron Lett. 2005, 46, 6765-6769.
26. Huang, F.; Slebodnick, C.; Rheingold, A. L.; Switek, K. A.; Gibson, H. W.* [2]Pseudorotaxanes Based on the Cryptand/Monopyridinium Recognition Motif. Tetrahedron 2005, 61, 10242-10253.
27. Huang, F.;* Slebodnick, C.; Switek, K. A.; Gibson, H. W.* Bis(m-phenylene)-32-Crown-10-Based Cryptand/Diquat Inclusion [2]Complexes. Chem. Commun. 2006, 1929-1931.
28. Huang, F.;* Yang, H.-B.; Das, N.; Maran, U.; Arif, A. M.; Gibson, H. W.; Stang, P. J. Incorporating a Flexible Crown Ether into Neutral Discrete Self-Assemblies Driven by Metal-Coordination. J. Org. Chem. 2006, 71, 6623-6625.
29. Yang, H.-B.; Das, N.; Huang, F.; Hawkridge, A. M.; Muddiman, D. C.; Stang, P. J.* Molecular Architecture via Coordination: Self-Assembly of Nanoscale Hexagonal Metallodendrimers with Designed Building Blocks. J. Am. Chem. Soc. 2006, 128, 10014-10015.
30. Yang, H.-B.; Das, N.; Huang, F.; Hawkridge, A. M.; Diaz, D. D.; Arif, A. M.; Finn, M. G.; Muddiman, D. C.; Stang, P. J.* Incorporation of 2,6-Di(4,4'-dipyridyl)-9-thiabicyclo[3.3.1]nonane into Discrete 2D Supramolecules via Coordination-Driven Self-Assembly. J. Org. Chem. 2006, 71, 6644-6647.
31. Huang, F.;* Gantzel, P.; Nagvekar, D. S.; Rheingold, A. L.; Gibson, H. W.* Taco Grande: a Dumbbell Bis(crown ether)/Paraquat [3](Taco Complex). Tetrahedron Lett. 2006, 47, 7841-7844.
32. Huang, F.;* Slebodnick, C.; Switek, K. A.; Gibson, H. W.* Inclusion [2]Complexes Based on the Cryptand/Diquat Recognition Motif. Tetrahedron 2007, 63, 2829-2839.
33. Huang, F.;* Slebodnick, C.; Mahan, E. J.; Gibson, H. W.* [3]Pseudorotaxanes Based on the Cryptand/Monopyridinium Salt Recognition Motif. Tetrahedron 2007, 63, 2875-2881.
34. Huang, F.;* Nagvekar, D. S.; Zhou, X.; Gibson, H. W.* Formation of a Linear Supramolecular Polymer by Self-Assembly of Two Homoditopic Monomers Based on the Bis(m-phenylene)-32-crown-10/Paraquat Recognition Motif. Macromolecules 2007, 40, 3561-3567.
35. Huang, F.; Pederson, A. M.; Gibson, H. W.* Polyrotaxanes. In Physical Properties of Polymers Handbook; Mark, J. E. Ed.; Springer-Verlag: New York, 2007; 693.
36. Huang, F.;* Jones, J. W.; Gibson, H. W.* Competitive Interactions of Two Ion-Paired Salts with a Neutral Host to Form Two Non-Ion-Paired Complexes. J. Org. Chem. 2007, 72, 6573-6576.
37. Zhang, X.; Zhai, C.; Li, N.; Liu, M.; Li, S.; Zhu, K.; Zhang, J.; Huang, F.;* Gibson, H. W. Host Size Effect in the Complexation of Two Bis(m-phenylene)-32-crown-10-Based Cryptands with a Diazapyrenium Salt. Tetrahedron Lett. 2007, 48, 7537-7541.
38. Zhang, J.; Huang, F.;* Li, N.; Wang, H.; Gibson, H. W.;* Gantzel, P.; Rheingold, A. L. Paraquat Substituent Effect on Complexation with a Dibenzo-24-crown-8-Based Cryptand. J. Org. Chem. 2007, 72, 8935-8938.
39. Zhang, C.; Li, S.; Zhang, J.; Zhu, K.; Li, N.; Huang, F.* Benzo-21-crown-7/Dialkylammonium Salt [2]Pseudorotaxane- and [2]Rotaxane-Type Threaded Structures. Org. Lett. 2007, 9, 5553-5556.
40. Li, S.; Liu, M.; Zhang, J.; Zheng, B.; Zhang, C.; Wen, X.; Li, N.; Huang, F.* High-yield Preparation of [2]Rotaxanes Based on the Bis(m-phenylene)-32-Crown-10-Based Cryptand/Paraquat Derivative Recognition Motif. Org. Biomol. Chem. 2008, 6, 2103-2107.
41. Zhang, J.; Zhai, C.; Wang, F.; Zhang, C.; Li, S.; Zhang, M.; Li, N.; Huang, F.* A Bis(m-phenylene)-32-crown-10-Based Fluorescence Chemosensor for Paraquat and Diquat. Tetrahedron Lett. 2008, 49, 5009-5012.
42. Pederson, A. M.-P.; Vetor, R. C.; Rouser, M. A.; Huang, F.; Slebodnick, C.; Schoonover, D. V.; Gibson, H. W.* A New Functional Bis(m-phenylene)-32-crown-10-Based Cryptand Host for Paraquats. J. Org. Chem. 2008, 73, 5570-5573.
43. He, C.; Shi, Z.; Zhou, Q.; Li, S.; Li, N.; Huang, F.* Syntheses of cis- and trans-Dibenzo-30-crown-10 Derivatives via Regioselective Routes and Their Complexations with Paraquat and Diquat. J. Org. Chem. 2008, 73, 5872-5880.
44. Wang, F.; Han, C.; He, C.; Zhou, Q.; Zhang, J.; Wang, C.; Li, N.; Huang, F.* Self-Sorting Organization of Two Heteroditopic Monomers to Supramolecular Alternating Copolymers. J. Am. Chem. Soc. 2008, 130, 11254-11255 (Highlighted by Vicki, C. Molecular self-assembly: Sort it out! Nature China 2008, 20 August).
45. Zhang, C.; Zhu, K.; Li, S.; Zhang, J.; Wang, F.; Liu, M.; Li, N.; Huang, F.* Binding of secondary dialkylammonium salts by pyrido-21-crown-7. Tetrahedron Lett. 2008, 49, 6917-6920.
46. Zhu, K.; Zhang, M.; Wang, F.; Li, N.; Li, S.; Huang, F.* Improved Complexation between Dibenzo-24-crown-8 Derivatives and Dibenzylammonium Salts by Ion-Pair Recognition. New J. Chem. 2008, 32, 1827-1830.
47. Li, S.; Liu, M.; Zhang, J.; Zheng, B.; Wen, X.; Li, N.; Huang, F.* Preparation of Bis(m-phenylene)-32-crown-10-Based Cryptand/Bisparaquat [3]Rotaxanes with High Efficiency. Eur. J. Org. Chem. 2008, 6128-6133.
48. Zhou, Q.; He, C.; Zhai, C.; Huang, F.* Templated Syntheses of Molecules with Mechanically Interlocked Structures. Huaxue Tongbao 2008, 71, 809-815.
49. Wang, F.; Zhou, Q.; Zhu, K.; Li, S.; Wang, C.; Liu, M.; Li, N.; Fronczek, F. R.; Huang, F.* Efficient Syntheses of Bis(m-phenylene)-26-crown-8-Based Cryptand/Paraquat [2]Rotaxanes by Immediate Solvent Evaporation Method. Tetrahedron 2009, 65, 1488-1494.
50. Li, S.; Zhu, K.; Zheng, B.; Wen, X.; Li, N.; Huang, F.* A Bis(m-phenylene)-32-crown-10/Paraquat [2]Rotaxane. Eur. J. Org. Chem. 2009, 1053-1057.
51. Zhu, K.; Li, S.; Wang, F.; Huang, F.* Anion-Controlled Ion-Pair Recognition of Paraquat by a Bis(m-phenylene)-32-crown-10 Derivative Heteroditopic Host. J. Org. Chem. 2009, 74, 1322-1328.
52. Liu, M.; Li, S.; Zhang, M.; Zhou, Q.; Wang, F.; Hu, M.; Fronczek, F. R.; Li, N.; Huang, F.* Three-Dimensional Bis(m-phenylene)-32-crown-10-Based Cryptand/Paraquat Catenanes. Org. Biomol. Chem. 2009, 7, 1288-1291.
53. Ge, Z.; Hu, J.; Huang, F.;* Liu, S.* Responsive Supramolecular Gels Constructed by Crown Ether Based Molecular Recognition. Angew. Chem. 2009, 121, 1830-1834; Angew. Chem. Int. Ed. 2009, 48, 1798-1802.
54. Zhu, K.; He, J.; Li, S.; Liu, M.; Wang, F.; Zhang, M.; Abliz, Z.; Yang, H.; Li, N.; Huang, F.* Synthesis of Bis(m-phenylene)-32-crown-10-Based Discrete Rhomboids Driven by Metal-Coordination and Complexation with Paraquat. J. Org. Chem. 2009, 74, 3905-3912.
55. Wang, F.; Zheng, B.; Zhu, K.; Zhou, Q.; Zhai, C.; Li, S.; Li, N.; Huang, F.* Formation of Linear Main-Chain Polypseudorotaxanes with Supramolecular Polymer Backbones via Two Self-Sorting Host-Guest Recognition Motifs. Chem. Commun. 2009, 4375-4377.
56. Gibson, H. W.;* Farcas, A.; Jones, J. W.; Ge, Z.; Huang, F.; Vergne, M.; Hercules, D. M. Supramacromolecular self-assembly: Chain extension, star and block polymers via pseudorotaxane formation from well-defined end-functionalized polymers. J. Polym. Sci., Part A: Polym. Chem. 2009, 47, 3518-3543.
57. Li, S.; Liu, M.; Zheng, B.; Zhu, K.; Wang, F.; Li, N.; Zhao, X.; Huang, F.* Taco Complex Templated Syntheses of a Cryptand/Paraquat [2]Rotaxane and [2]Catenane by Olefin Metathesis. Org. Lett. 2009, 11, 3350-3353.
58. Li, S.; Huang, F.;* Slebodnick, C.; Ashraf-Khorassani, M.; Gibson, H. W.* Complexes of Diquat with Dibenzo-24-Crown-8. Chin. J. Chem. 2009, 27, 1777-1781.
59. Wang, F.; Zhang, J.; Ding, X.; Dong, S.; Liu, M.; Zheng, B.; Li, S.; Wu, L.; Yu, Y.; Gibson, H. W.; Huang, F.* Metal-Coordination-Mediated Reversible Conversion between Linear and Crosslinked Supramolecular Polymers. Angew. Chem. 2010, 122, 1108-1112; Angew. Chem. Int. Ed. 2010, 49, 1090-1094 (Highlighted by Swager, T. M. Reversible Conversion between Linear and Cross-Linked Supramolecular Polymers. Synfacts 2010, 0542-0542).
60. Liu, M.; Li, S.; Hu, M.; Wang, F.; Huang, F.* Selectivity Algorithm for the Formation of Two Cryptand/Paraquat Catenanes. Org. Lett. 2010, 12, 760-763.
61. Li, S.;* Zheng, B.; Huang, F.; Zakharov, L. N.; Slebodnick, C.; Rheingold, A. L.; Gibson, H. W. A new cryptand/paraquat [2]pseudorotaxane. Sci. China Ser. B-Chem. 2010, 53, 858-862.
62. Zhu, K.; Wu, L.; Yan, X.; Zheng, B.; Zhang, M.; Huang, F.* Anion Assisted Complexation of Paraquat by Bis(m-phenylene)-32-crown-10-Based Cryptands. Chem. Eur. J. 2010, 16, 6088-6098.
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81. Zhang, M.; Zheng, B.; Huang, F.* Synthesis of a Four-armed Cage Molecule and Its pH-Controlled Complexation with Paraquat. Chem. Commun. 2011, 47, 10103-10105.
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85. Zhang, M.; Li, S.; Dong, S.; Chen, J.; Zheng, B.; Huang, F.* Preparation of a Daisy Chain via Threading-Followed-by-Polymerization. Macromolecules 2011, 44, 9629-9634.
86. Chang, K.; Chen, W.;* Ma, L.; Li, H.; Li, H.; Huang, F.; Xu, Z.; Zhang, Q.; Lee, J.-Y. Graphene-like MoS2/Amorphous Carbon Composites with High Capacity and Excellent Stability as Anode Materials for Lithium Ion Batteries. J. Mater. Chem. 2011, 21, 6251-6257.
87. Niu, Z.; Slebodnick, C.; Huang, F.; Azurmendi, H.; Gibson, H. W.* An Acid–Base Adjustable Pseudocryptand-type [2]Pseudorotaxane Based on a Bis(meta-phenylene)-32-Crown-10 Derivative and Paraquat. Tetrahedron Lett. 2011, 52, 6379-6382.
88. Chen, J.; Yan, X.; Zhao, Q.; Li, L.;* Huang, F.* Adjustable Supramolecular Polymer Microstructures Fabricated by the Breath-figure Method. Polym. Chem. 2012, 3, 458-462.
89. Yan, X.; Xu, D.; Chi, X.; Chen, J.; Dong, S.; Ding, X.; Yu, Y.; Huang, F.* A Multiresponsive, Shape-Persistent, and Elastic Supramolecular Polymer Network Gel Constructed by Orthogonal Self-Assembly. Adv. Mater. 2012, 24, 362-369.
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93. Dong, S.; Yan, X.; Zheng, B.; Chen, J.; Ding, X.; Yu, Y.; Xu, D.; Zhang, M.; Huang, F.* A Supramolecular Polymer Blend Containing Two Different Supramolecular Polymers via Self-Sorting Organization of Two Heteroditopic Monomers. Chem. Eur. J. 2012, 18, 4195-4199.
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95. Ma, Y.; Chi, X.; Yan, X.; Liu, J.; Yao, Y.; Chen, W.; Hou, J.-L.;* Huang, F.* per-Hydroxylated Pillar[6]arene: Synthesis, X-ray Crystal Structure and Host-Guest Complexation. Org. Lett. 2012, 14, 1532-1535.
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101. Yao, Y.; Xue, M.; Chi, X.; Ma, Y.; He, J.; Abliz, Z.; Huang, F.* A New Water-Soluble Pillar[5]arene: Synthesis and Application in the Preparation of Gold Nanoparticles. Chem. Commun. 2012, 48, 6505-6507.
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107. Zhang, Z.; Han, C.; Yu, G.; Huang, F.* A Solvent-Driven Molecular Spring. Chem. Sci. 2012, 3, 3026-3031.
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110. Han, C.; Zhang, Z.; Chi, X.; Zhang, M.; Yu, G.; Huang, F.* Synthesis of 1,4-bis(n-propoxy)pillar[7]arene and its host-guest chemistry. Acta Chim. Sinica 2012, 70, 1775-1778.
111. Yan, X.; Chi, X.; Wei, P.; Zhang, M.; Huang, F.* [n]Pseudorotaxanes (n = 2,3) from Self-Assembly of Two Cryptands and a 1,2-Bis(4-pyridinium)ethane Derivative. Eur. J. Org. Chem. 2012, 6351-6356.
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113. Han, C.; Zhang, Z.; Yu, G.; Huang, F.* Syntheses of a Pillar[4]arene[1]quinone and a Difunctionalized Pillar[5]arene by Partial Oxidation. Chem. Commun. 2012, 48, 9876-9878.
114. Yao, Y.; Xue, M.; Chen, J.; Zhang, M.; Huang, F.* An Amphiphilic Pillar[5]arene: Synthesis, Controllable Self-Assembly in Water, and Application in Calcein Release and TNT Adsorption. J. Am. Chem. Soc. 2012, 134, 15712–15715.
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117. Dong, S.; Zheng, B.; Zhang, M.; Yan, X.; Ding, X.; Yu, Y.; Huang, F.* Preparation of a Diblock Supramolecular Copolymer via Self-Sorting Organization. Macromolecules 2012, 45, 9070-9075.
118. Yu, G.; Zhou, X.; Zhang, Z.; Han, C.; Mao, Z.; Gao, C.; Huang, F.* Pillar[6]arene/Paraquat Molecular Recognition in Water: High Binding Strength, pH-Responsiveness and Application in Controllable Self-Assembly, Controlled Release and Treatment of Paraquat Poisoning. J. Am. Chem. Soc. 2012, 134, 19489-19497.
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120. Ji, X.; Yao, Y.; Li, J.; Yan, X.; Huang, F.* A Supramolecular Cross-Linked Conjugated Polymer Network for Multiple Fluorescent Sensing. J. Am. Chem. Soc. 2013, 135, 74-77.
121. Wei, P.; Yan, X.; Li, J.; Ma, Y.; Huang, F.* Two 2:3 Copillar[5]arene Constitutional Isomers: Syntheses, Crystal Structures and Host-Guest Complexation of Their Derivatives with Dicarboxylic Acid Sodium Salts in Water. Chem. Commun. 2013, 49, 1070-1072.
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142. Yan, X.; Li, S.; Cook, T. R.; Ji, X.; Yao, Y.; Pollock, J. B.; Shi, Y.; Yu, G.; Li, J.; Huang, F.;* Stang, P. J.* Hierarchical Self-Assembly: Well-Defined Supramolecular Nanostructures and Metallohydrogels via Amphiphilic Discrete Organoplatinum(II) Metallacycles. J. Am. Chem. Soc. 2013, 135, 14036-14039.
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372. Li, B.;# Li, Q.;# Qi, Z.; Li, Z.; Yan, X.; Chen, Y.; Xu, X.; Pan, Q.; Chen, Y.; Huang, F.;* Ping, Y.* Supramolecular Genome Editing: Targeted Delivery and EndogenousActivation of CRISPR/Cas9 by Dynamic Host-Guest Recognition. Angew. Chem. Int. Ed. 2024, 63, e202316323.
373. Yan, M.; Wu, S.; Wang, Y.; Liang, M.; Wang, M.; Hu, W.; Yu, G.;* Mao, Z.;* Huang, F.;* Zhou, J.* Recent Progress of Supramolecular Chemotherapy Based on Host–Guest Interactions. Adv. Mater. 2024, 36, 2304249.
374. Xu, D.; Li, Y.; Yin, S.* Huang, F.* Strategies to Address Key Challenges of Metallacycle/Metallacage-based Supramolecular Coordination Complexes in Biomedical Applications. Chem. Soc. Rev. 2024, 53. 3167-3204.
375. Shan, T.; Chen, L.; Xiao, D.; Xiao, X.; Wang, J.; Chen, X.; Guo, Q.; Li, G.;* Stoddart, J. F.;* Huang, F.* Adaptisorption of Nonporous Polymer Crystals. Angew. Chem. Int. Ed. 2024, 136, e202317947.
376. Yang, K.; Bai, B.; Huang, F.;* Yu, G.* Drug-Initiated Poly(thiocitc acid) Polymer Incorporating Host-Guest Interaction for Cancer Combination Chemotherapy. iScience, 2024, 27, 109070.
377. Yang, K.; Bai, B.; Lei, J.; Yu, X.; Qi, S.; Wang, Y.; Huang, F.; Tong, Z.; Yu, G.* Biodegradable Lipid-Modified Poly(Guanidine Thioctic Acid)s: A Fortifier of Lipid Nanoparticles to Promote the Efficacy and Safety of mRNA Cancer Vaccines. J. Am. Chem. Soc. 2024, 146, 11679-11693.
378. Hu, W.; Ye, B.; Yu, G.; Yang, H.; Wu, H.; Ding, Y.; Huang, F.; Wang, W.*; Mao, Z.*. Dual-Responsive Supramolecular Polymeric Nanomedicine for Self-Cascade Amplified Cancer Immunotherapy. Adv. Sci. 2024, 11. 2305382.
379. Liu, Z.; Li, M.;* Fang, S.; Shao, L.;* Hua, B.;* Huang, F.* Highly selective separation of toluene/methylcyclohexane based on pagoda[5]arene nonporous adaptive crystals. Org. Chem. Front., 2024, 11, 2756-2761.
380. Sheng, X.;# Wang, Z.;# Sheng, G.;# Zhu, C.; Xiao, D.; Shan, T.; Xiao, X.; Liu, M.; Li, G.;* Zhu, Y.;* Sessler, J. L.;* Huang, F.* Three-Dimensional Crystalline Organic Framework Stabilized by Molecular Mortise-and-Tenon Jointing. J. Am. Chem. Soc. 2024, 146, 12547-12555.
381. Li, Y.; Huang, F.;* Stang, P. J.;* Yin, S.* Supramolecular Coordination Complexes for Synergistic Cancer Therapy. Acc. Chem. Res. 2024, 57, 1174-1187.
382. He, L.; Jiang, Y.; Wei, J.; Zhang, Z.; Hong, T.; Ren, Z.; Huang, J.;* Huang, F.;* Stang, P. J.;* Li, S.* Highly robust supramolecular polymer networks crosslinked by a tiny amount of metallacycles. Nat. Commun. 2024, 15, 3050.
383. Nazarova, A.;* Mostovaya, O.; Bukharov, M.; Nagaeva, A.; Yusupov, G.; Zelenikhin, P.; Hua, B.; Huang, F.; Padnya, P.; Stoikov, I.* Peptidomimetics based on pillar[5]arene: Charge effect on self-assembly, toxicity, and herbicide binding. Colloid Surf. A-Physicochem. Eng. Asp. 2024, 693, 134050.
384. Wang, J.; You, W.; Chen, L.; Xiao, D.; Xiao, X.; Shan, T.; Liu, Y.; Liu, M.; Li, G.;* Yu, W.;* Huang, F.* Adaptive and Robust Vitrimers Fabricated by Synergy of Traditional and Supramolecular Polymers. Angew. Chem. Int. Ed. 2024, 63, e202405761.
385. Xiao, X.; Xu, D.; Han, H.; Wang, D.; Lei, S.; Liu, R.; Hu, N;* Sessler, J.;* Huang, F.* Sensitive Intracellular Recording of Action Potentials by Supramolecular Self-Assembled Electrodes. Adv. Funct. Mater. 2024, 202404634.
386. Fan, G.; Zhang, Z.; Wang, G.; Shao, L.; Hua, B.;* Huang, F.* Construction of hydrocarbon belts based on macrocyclic arenes. Chem. Sci. 2024, 15, 10713-10723.
387. Zhang, Y.; Liu, Y.; Wu, Y.; Ge, C.; Li, B.; Wei, Y.; Qian, Y.; Li, Q.;* Huang, F.;* Li, H.* A Tetracationic Cyclophane. CCS Chem. 2024, 6, DOI:10.31635/ccschem.024.202404345.
388. Ye, B.; Hu, W.;* Yu, G.; Yang, H.; Gao, B.; Ji, J.; Mao, Z.;* Huang, F.; Wang, W.;* Ding, Y.* A Cascade-Amplified Pyroptosis Inducer: Optimizing Oxidative Stress Microenvironment by Self-Supplying Reactive Nitrogen Species Enables Potent Cancer Immunotherapy. ACS Nano 2024, 18, 16967-16981.
389. Wang, Y.;* Huang, F.* Highly site-selective C(sp3)–H bond functionalization enabled by framework confinements. Chem Catalysis 2024, 4, DOI: 10.1016/j.checat.2024.100961.
390. Liu, X.; Liu, X.; Zheng, H.; Lu, K.; Chen, D.; Xiong, C.; Huang, F.; Zhang, L.;* Zhang, D.* Improvement of hydrophilicity and formation of heparin/chitosan coating inhibits stone formation in ureteral stents. Colloid Surf. A-Physicochem. Eng. Asp. 2024, 694.
391. Xiao, M.; Liu, Z.; Liu, P.; Fang, S.; Shao, L.; Hua, B.;* Liu, Y.;* Huang, F.* A Pillararene-Based Cavitand: Synthesis and Solid-State Capsular Assemblies Induced by Linear Alkanes with Specific Lengths. Org. Lett. 2024, 26, 6220-6224.
392. Xiao, D.;# Jin, Z.;# Sheng, G.;# Chen, L.; Xiao, X.; Shan, T.; Wang, J.; Navik, R.; Xu, J.; Zhou, L.; Guo, Q.-H.; Li, G.;* Zhu, Y.;* Stoddart, J. F.;* Huang, F.* Single crystals of purely organic free-standing two-dimensional woven polymer networks. Nat. Chem. 2024, 16, 1906-1914.
393. Li, Y.; Li, S.; Wang, M.; Shao, L.; Fang, S.;* Hua, B.;* Huang, F.* Two pyrene-based cagearene constitutional isomers: synthesis, separation, and host–guest chemistry. Org. Chem. Front. 2024, 11, 4992-4996.
394. Wang, Y.; Zhang, J.; Xu, Q.; Tu, W.; Wang, L.; Xie, Y.; Sun, J.; Huang, F.; Zhang, H.;* Tang, B.* Narrowband clusteroluminescence with 100% quantum yield enabled by through-space conjugation of asymmetric conformation. Nat. Commun. 2024, 15, 6426.
395. Wang, Z.;# Wu, Y.;# Zhang, Z.; Sheng, X.; Fang, S.; Liu, Y.; Gong, Y.; Wang, M.; Song, N.;* Huang, F.* A Pillar[5]arene-Containing Metal-Organic Framework for Rapid and Highly-Capable Adsorption of a Mustard Gas Stimulant. J. Am. Chem. Soc. 2024, 146, 23330-23337.
396. He, L.; Wei, J.; Zhang, Z.; Shentu, N.; Wang, J.; Yu, J.; Ren, Z.; Liu, J.; Li, G.; Huang, F.; Li, S.* Improvement of Polymer Mechanical Behaviors by Introducing [2]Rotaxane Units with Intra- and Intermolecular Hydrogen Bonds. Macromolecules 2024, 57, 7777-7786.
397. Li, M.; Yang, Y.; Liu, R.; Wang, Y.; Shao, L.; Hua, B.;* Liu, X.;* Huang, F.* Pillar[5]arene-Based Ion-Pair Recognition for Encapsulation of a Stilbazolium-Type Dye with Enhanced Photophysical Properties and Nonlinear Optical Activity. Chem.-Eur. J. 2024, 30, e202402345.
398. Chen, L.; Tan, M.; Jin, J.; Zhang, Z.; Huang, F.; Li, S.;* Li, Y.* Synthesis and Application of Chiral Organic Imine Molecular Cages. Chin. J. Org. Chem. 2024, 44, 2617-2639.
399. Zhu, W.;#,* Zhao, B.;# Zhu, H.;* Huang, F.* Anthracene-containing crown ether: synthesis, host–guest properties and modulation of solid-state luminescence. Chem. Sci. 2024, 15, 16300-16306.
400. Xu, J.; Wang, T.; Deng, S.; Lai, W.; Shi, Y.; Zhao, Y.; Huang, F.;* Wei, P.* Visible Light-Responsive Crystalline B←N Host Adducts with Solvent-Induced Allosteric Effect for Guest Release. Angew. Chem. Int. Ed. 2024, 63, DOI: 10.1002/anie.202411880.
401. Chen, L.;# Liu, Y.;# You, W.;# Wang, J.; He, Z.; Mei, H.; Yang, X.; Yu, W.; Li, G.;* Huang, F.* Construction of Slide-Ring Polymers Based on Pillar[5]arene/Alkyl Chain Host-Guest Interactions Angew. Chem. Int. Ed. 2024, 63, e202417713.
402. Liu, T.;# Zhu, L.;# Liu, K.; Liu, Z.; Liu, Y.; Zhang, Y.; Hu, Y.;* Guo, Q.;* Huang, F.* Diameter-Controlled Synthesis of Carbon Nanotubes Using [2n]Collarenes as Rigid Organic Templates. J. Am. Chem. Soc. 2024, 146, 32445-32451.
403. Shurpik, D. N.;* Aleksandrova, Y. I.; Makhmutova, L. I.; Akhmedov, A. A.; Nazarova, A. A.; Lodochnikova, O. A.; Ivshin, K.; Kataeva, O. N.; Islamov, D. R.; Huang, F.; Stoikov, I. I.* Supramolecular Self-Assembly of Monosubstituted Pillar[5]Arenes Under the Control of the Nature of the Amide Moiety. ChemistrySelect. 2025, 10, e202405414.
404. He, L.; Wei, J.; Ren, Z.; Li, Y.; Zhang, Z.;* Li, G.; Huang, F.; Li, S.* Polyurethane Elastomers Strengthened by Pseudo[1]rotaxanes Based on Pillararenes. Angew. Chem. Int. Ed. 2025, 64, e202421557.
405. Wang, Z.;# Zhao, L.;# Zhang, Z.;# Sheng, X.; Yue, H.; Liu, R.; Liu, Z.; Li, Y.; Shao, L.; Peng, Y.;* Hua, B.;* Huang, F.* Superhydrophobic and Self-Healing Porous Organic Macrocycle Crystals for Methane Purification under Humid Conditions. J. Am. Chem. Soc. 2025, 147, 5, 4210–4218.
406. Wu, Y.; Tang, M.; Barsoum, M. L.; Chen, Z.;* Huang, F.* Functional crystalline porous framework materials based on supramolecular macrocycles. Chem. Soc. Rev., 2025, 54, 2906–2947.
407. Xu, Z.; Ying, X.; Li, Y.; Dong, X.; Liu, J.; Wang, S.; Little, M. A.; Zhang, D.; Xie, Y.; Zhang, Z.; Yu, L.; Huang, F.; Li, S.* Template-directed self-assembly of porphyrin nanorings through an imine condensation reaction. Chem. Sci., 2025, 16, 5166–5173.
408. Fang, B.; Pan, F.; Shan, T.; Chen, H.; Peng, W.; Tian, W.; Huang, F.;* Mao, Z.;* Ding, Y.* An Integrated Virtual Screening Platform to Identify Potent Co-Assembled Nanodrugs for Cancer Treatment. Adv. Mater. 2025, 37, 2414154.
409. Zhou, D.; Ma, M.; Liu, J.; Sheng, Y.; Zhang, P.; Wang, S.; Huang, F.; Li, S.;* Zhang, Z.* Influence of Pillararene-Based Host-Guest Chemistry on the Enantioselective Synthesis of 2,3-Dihydroquinazolinones. Eur. J. Org. Chem. 2025, 28, e202500081
410. Wu, Y.;# Shi, L.;# Xu, L.;# Ying, J.; Miao, X.; Hua, B.;* Chen, Z.;* Sessler, J. L.;* Huang, F.* Supramolecular docking structure determination of alkyl-bearing molecules. Nature 2025, 640, 676–682.
411. Liu, Y.; Qian, Y.; Chen, L.; Ge, C.; Zhang, Y.; Tang, H.; Fang, S.; * Li, Q.; * Huang, F.; Li, H.* Self-Sorting via Macrocyclization by External Templation in Water. Org. Lett. 2025, 27, 5027−5031.
412. Shan, T.;# Chen, L.;# Guo, Z.;# Xiao, D.; Wang, M.; Xiao, X.; Li, G.;* Huang, F.* Designing High-Mechanical-Property Organic Polymeric Crystals: Insights from Stress Dispersion and Energy Dissipation Strategies. J. Am. Chem. Soc. 2025, 147, 17477-17485.
413. Zhang, H.; Li, M.; Shao, L.; Liang H.; Hua, B.;* Khashab, N. M.;* Huang, F.* Selective separation of meta- and para-cresol using nonporous adaptive crystals of perpropoxylated pillar[5]arene. Org. Chem. Front. 2025, 12, 5205-5210.
414. Shan, T.;# Ju, Z.;# Xiao, D.;# Yue. K.;# Cui, Z.; Zhang, Y.; Chi, X.; Fan, X.; Li, G.;* Tao, X.;* Huang, F.* Molecularly Woven Artificial Solid Electrolyte Interphase. Angew. Chem. Int. Ed. 2025, 64, e202505056.
415. Zhang, Z.; Ju, H.; Zhang, H.; Wang, Z.;* Du, M.; Li, H.; Huang, F.; Zheng, Q.; Wu, Z.* Polymerization-Induced Crystallization to Form Stretchable Hydrogels with Banded Spherulites and Circularly Polarized Luminescence. Adv. Mater. 2025, 37, 2505444.
416. Mei, H.;# Liu, C.;# Jiang, N.; Wang, J.; He, Z.; Yang, X.; Wang, Y.; Zhao, D.; Wang, Y.; Zhang, S.;* Li, G.;* Huang, F.* Robust Ionic Gel Elastomers Derived from Molecularly Entangled Nodes. Angew. Chem. Int. Ed. 2025, 64, e202506559.
417. Fang, B.;# Shan, T.;# Chen, S.;# Pan, F.; Yang, X.; Xiao, D.; Huang, F.;* Mao, Z.* Mesoporous Potassium-Based Metal-Organic Framework as a Drug Carrier. ACS Cent. Sci. 2025, 11, 1651−1658.
418. Liu, R.; Mei, Z.; Li, M.; Xiao, M.; Wang, G.; Liu, Z.; Shao, L.; Liang, H.; Huang, F.; Liu, X.;* Hua, B.* Molecular Alignment of 4‑(Dimethylamino)-4′-Nitroazobenzene Molecules through Pillararene-Based Host−Guest Complexation for Improvement of Nonlinear Optical Properties. Cryst. Growth Des. 2025, 25, 6994−6998.
419. Tan, S.; # Han, Y.; # Wang, G; Chen, L; Shao, L; Xiao, M; Zhao, B; Huang, F; * Hua, B; * Social Chiral Self-Sorting Synthesis of [9]Cycloparaphenylene-Pillar[5]arene Heterochiral Multicavity Macrocyclic Trimers with Circularly Polarized Luminescence. Angew. Chem. Int. Ed. 2025, 64, e202508361.
420. Fang, S.; # Wang, M.; # Tang, C.; # Wu, G.; Liu, E.; Han, H.; Zhao, B.; Li, S.; Xiao, M.; Li, M.; Zhao, X.; Liu, B.; Tang, B.; Shi, C.; Stoddart, J. F.; Sessler, J. L.;* Huang, F.* Cation Recognition by a Cationic Capsule Through Anion-Induced Allosteric Regulation. CCS Chem. 2025, 7, 3015–3024.
421. Zhou, P.;# Cao, J.;# Cheng, K.; Hua, B.; Huang, F.;* Chen, H.* Tunable Multistate Mechanoresistance in a Single-Molecule Junction Incorporating Energy-Dissipative Structures. Angew. Chem. Int. Ed. 2025, 64, e202514423.
422. Zhang, S.; Wei, Y.; Chen, Q.; Qian, Y.; Wu, G.; Ge, C.; Huang, F.; Li, H.* Pretzelanes with Planar Chirality and Guest Recognition Capabilities. J. Am. Chem. Soc. 2025, 147, 36843−36850.
423. Xiao, M.; Liu, Z.; Tan, S.; Zhao, B.; Chen, L.; Liu, Z.; Zhang, Y.; Fang, S.;* Shao, L.; Liu, Y.; Hua, B.;* Huang, F.;* Pillar[5]arene-based visual planar chirality switches with variable color expression J. Am. Chem. Soc. 2025, 147, 40917–40924.
424. He, Z.;# Chen, L.;# You, W.;# Zhu, C.; Yang, X.; Mei, H.; Xiao, D.; Song, Q.; Shan, T.; Yu, W.; Li, G.;* Huang, F.* Weaving-inspired asymmetric entangled nodes in multi-component polymer networks. Nat. Mater. 2025, DOI: 10.1038/s41563-025-02400-w.
425. Xiao, D.;# Hu, D.;# Yang, S.;# Yang, X.;# Guo, Z.; Chen, L.; Navik, R.; Shan, T.; Pan, Y.; Miao, X.; Liu, M.;* Li, G.;* Huang, F.* Dynamic separation of water isotopologues by a porous molecularly woven fabric. Nat. Synth. 2025, DOI: 10.1038/s44160-025-00913-5.
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1973年出生。1996年7月本科毕业于合肥工业大学。1999年7月获得中国科学技术大学高分子化学与物理硕士学位,导师为何平笙教授和阮德礼教授。2005年3月获Virginia Polytechnic Institute & State University有机与高分子化学博士学位,导师为Harry W. Gibson教授。后在University of Utah化学系从事博士后工作,导师为Peter J. Stang教授。2005年12月起任浙江大学化学系教授,筹建超分子化学研究小组。2008年3月起任浙江大学求是特聘教授。2018年5月起任浙江大学长江学者特聘教授。主要从事超分子化学方面的研究工作,当前的主要研究兴趣包括超分子聚合物、超分子两亲分子、柱芳烃超分子化学、以及非多孔自适应晶体(简称:纳客;英文全称:nonporous adaptive crystals;英文简称:NACs)、纳米碳。已发表超分子化学相关论文458篇,包括1篇Nature、2篇Nature Chemistry、1篇Nature Materials、1篇Nature Synthesis、1篇Nature Review Chemistry、3篇PNAS、67篇Journal of the American Chemical Society、31篇Angewandte Chemie International Edition、16篇Advanced Materials、1篇Chem、和9篇Nature Communications。发表的论文已被引用46673次,H-index为121。两篇通讯作者论文入选“中国百篇最具影响国际学术论文”。2015年至今连年入选科睿唯安全球“高被引科学家”。到目前为止获得的主要奖励和荣誉有:2004年获国家优秀自费留学生奖学金和Virginia Polytechnic Institute & State University 优秀硕士论文William Preston 奖(William Preston Award for MS thesis),2005年获The Sigma Xi Society Research Award,2006年获Virginia Polytechnic Institute & State University优秀博士论文奖(Outstanding Dissertation Award),2006年入选浙江省“钱江人才计划”, 2007年获美国李氏基金会杰出成就奖并入选浙江省“新世纪151人才工程”,2008年被评选为浙江大学“十佳青年岗位能手”,2009年获Thieme Chemistry Journals Award并入选教育部 “新世纪优秀人才支持计划”,2010年获浙江省杰出青年科学基金项目资助和Virginia Polytechnic Institute & State University的 the Outstanding Recent Graduate Alumnus Award,2011年获国家杰出青年科学基金项目资助,指导博士生获得2011年全国百篇优秀博士论文提名奖,2012年入选英国皇家化学会会士(Fellow of the Royal Society of Chemistry, FRSC),2013年入选国家创新人才推进计划中青年科技创新领军人才,2013年入选亚洲化学大会Asian Rising Star,2013年获得浙江省青年科技奖,2014年获中国化学会-阿克苏诺贝尔化学奖,2015年获英国皇家化学会Cram Lehn Pedersen Prize in Supramolecular Chemistry,2016年获英国皇家化学会Polymer Chemistry Lectureship Award,2016年入选国家万人计划领军人才,2017年入选教育部长江学者奖励计划特聘教授,2018年获英国皇家学会Newton Advanced Fellowship,2019年获德国Bruno Werdelmann Lectureship Award,2019年获“浙江大学第六届师德先进个人”荣誉称号,2020年获教育部基础学科拔尖学生培养计划优秀导师奖,2020年入选浙江大学竺可桢学院年度最佳专业导师,2020年获浙江省自然科学奖一等奖(第一完成人),2023年入选中国化学会会士,2023年入选国务院政府特殊津贴专家。指导的博士生2015年(颜徐州)、2017年(揭克诚)、2021年(李二锐)、2024年(吴奕韬)、2025年(陈丽雅)五次获浙江大学优秀博士学位论文奖,四次(颜徐州、喻国灿、吉晓帆、周炯)获浙江大学竺可桢奖学金(每年最多十二名研究生可获该奖项),一次(吴奕韬,2024)获国家博新计划资助。应邀在国内外作学术报告240次,包括应邀到澳大利亚全国高分子会议上作学术报告,应邀在全国有机化学学术讨论会上作大会报告,应邀到第15届亚洲化学大会上作Asian Rising Stars分会邀请报告,应邀到韩国全国高分子会议上作学术报告,应邀在全国大环化学暨超分子化学学术讨论会上作大会报告,应邀在美国举行的第一届人工分子开关与马达高登会议(Gordon Research Conference)上作邀请报告,应邀在法国举行的第十届大环与超分子化学国际研讨会(ISMSC-10)上作大会报告,应邀在澳大利亚举行的第23届IUPAC国际物理有机化学会议上作大会报告,应邀在葡萄牙里斯本举行的第一届非共价相互作用国际会议上作大会报告,在英国考文垂举行的第50届IUPAC世界高分子大会上作大会报告。应邀担任Chemical Society Reviews、Accounts of Chemical Research、Chemical Reviews、Chemical Communications、Advanced Materials、和Materials Chemistry Frontiers的客座编辑。应邀担任Journal of the American Chemical Society(2020年起)、Chemical Society Reviews(2012年起)、Chemical Communications(2012年起)、化学学报(2012年-2018年)、Macromolecules (2014年-2017年)、ACS Macro Letters(2014年-2017年)、Polymer Chemistry(2014年起)、Materials Chemistry Frontiers(2016年起)、高分子学报(2016年起)、中国化学快报(2018年起)、Giant(2020年起)、Aggregate(2021年起)、Coordination Chemistry Reviews(2024年起)等的顾问编委或编委。现任国务院学位委员会化学学科评议组成员(2020年11月起)、中国化学会高分子学科委员会委员、中国化学会超分子化学专业委员会副主任委员、中国化学会晶体化学专业委员会委员、中国化学会分子聚集发光专业委员会委员、中国化学会分子医学专业委员会委员、中国化学会奖励推荐委员会委员、国际大环及超分子化学大会(ISMSC)国际科学委员会委员(2022年-2027年)、非共价相互作用国际会议国际顾问委员会委员(2019年起)、浙江省化学会理事、浙江大学新物质创制会聚研究计划(简称“天工计划”)首席科学家(2020年4月起)、浙江大学杭州国际科创中心超分子新物质创制创新工坊执行院长(2021年6月起)、九三学社浙江大学委员会副主委(2019年7月起)、九三学社浙江省委常委(2022年5月起)、九三学社浙江省委科技专门委员会主任(2022年9月起)、浙江-以色列自组装功能材料联合实验室主任(2022年12月起)、浙江省政协委员(2023年1月起)、浙江大学欧美同学会(留学人员联谊会)副会长(2023年1月起)、浙江大学杭州国际科创中心-杭州之江有机硅化工有限公司联合实验室主任(2023年1月起)、浙江省留学人员和家属联谊会副会长(2025年1月起)。
教学工作
高分子化学、超分子化学、化学选论
研究领域:超分子化学、超分子聚合物、主客体化学、超分子两亲分子、非多孔自适应晶体(NACs)、环状共轭分子。
具体方向:储能电池材料、工业催化、编织聚合物的构筑、框架材料、密封胶与粘接剂、化工分离、分子捕手、纳客。
工作研究项目
1. 基于分子尺度的运动构建具有宏观响应性的高分子,国家自然科学基金重点项目,22035006,起于2021年1月止于2025年12月,直接经费总额294万 (总经费352.8万),项目负责人。
2. 可应用于高附加值化学品转化的超分子智能分离材料的构筑,国家自然科学基金重点国际(地区)合作研究项目,22320102001,起于2024年1月止于2028年12月,直接经费216万 (总经费280.8万),项目负责人。
3. 主客体机械互锁结构增韧的环氧树脂,国家自然科学基金指南引导类原创探索计划项目,22350007,起于2024年1月止于2026年12月,直接经费300万 (总经费390万),项目负责人。
发表论文
1. Yuan, J.; Zuo, G.; Zuo, X.; Huang, F. Modification of Organic Glass and Its Progress. New Chemical Materials, 1996, 2-18.
2. Yuan, J.; Zuo, G.; Zuo, X.; Huang, F. Study on Surface Hardness of Organic Glass Prepared by Crosslinking Copolymerization. Modern Plastic Processing and Applications, 1997, 9, 15-17.
3. Yuan, J.; Zuo, G.; Zuo, X.; Huang, F. Study on Preparation and Properties of Copolymerized Crosslinked Organic Glass. Polymeric Materials Science and Engineering, 1999, 15, 154-156.
4. Zhang, Y.;* Huang, F.; Yuan, D. Study of Relationship of Structure and Properties of Photosensitive Prepolymer. Journal of China University of Science and Technology, 2000, 30, 201-207.
5. Huang, F.; Li, C.; He, P.* Cure Behavior of Interpenetrating Polymer Networks Studied by Dynamic Torsional Vibration Method. Polymeric Materials Science and Engineering, 2001, 17, 93-97.
6. Huang, F.; Fronczek, F. R.; Gibson, H. W.* First Supramolecular Poly(taco complex). Chem. Commun. 2003, 1480-1481.
7. Huang, F.; Fronczek, F. R.; Gibson, H. W.* A Cryptand/Bisparaquat [3]Pseudorotaxane by Cooperative Complexation. J. Am. Chem. Soc. 2003, 125, 9272-9273.
8. Huang, F.; Gibson, H. W.;* Bryant, W. S.; Nagvekar, D. S.; Fronczek, F. R. First Pseudorotaxane-Like [3]Complexes Based on Cryptands and Paraquat: Self-Assembly and Crystal Structures. J. Am. Chem. Soc. 2003, 125, 9367-9371.
9. Huang, F.; Zakharov, L. N.; Rheingold, A. L.; Jones, J. W.; Gibson, H. W.* Water Assisted Formation of a Pseudorotaxane and Its Dimer Based on a Supramolecular Cryptand. Chem. Commun. 2003, 2122-2123.
10. Gibson, H. W.;* Ge, Z. Huang, F.; Jones, J. W.; Wang, H.; Farcas, A. Mechanically Interlocked Macromolecular Systems via Pseudorotaxane Self-assembly. Polymer Preprints 2003, 44, 475-476.
11. Huang, F.; Jones, J. W.; Slebodnick, C.; Gibson, H. W.* Ion Pairing in Fast-Exchange Host-Guest Systems: Concentration Dependence of Apparent Association Constants for Complexes of Neutral Hosts and Divalent Guest Salts with Monovalent Counterions. J. Am. Chem. Soc. 2003, 125, 14458-14464.
12. Jones, J. W.; Huang, F.; Bryant, W. S.; Gibson, H. W.* A Cautionary Note Regarding the Investigation of Supramolecular Complexes Involving Secondary Ammonium Salts in Acetone. Tetrahedron Lett. 2004, 45, 5961-5963.
13. Huang, F.; Gibson, H. W.* Formation of a Supramolecular Hyperbranched Polymer from Self-Organization of an AB2 Monomer Containing a Crown Ether and Two Paraquat Moieties. J. Am. Chem. Soc. 2004, 126, 14738-14739.
14. Huang, F.; Zhou, L.; Jones, J. W.; Gibson, H. W.;* Ashraf-Khorassani, M. Formation of Dimers of Inclusion Cryptand/Paraquat Complexes Driven by Dipole-Dipole and Face-to-Face p-Stacking Interactions. Chem. Commun. 2004, 2670-2671.
15. Huang, F.; Nagvekar, D. S.; Slebodnick, C.; Gibson, H. W.* A Supramolecular Triarm Star Polymer from a Homotritopic Tris(Crown Ether) Host and a Complementary Monotopic Paraquat-Terminated Polystyrene Guest by a Supramolecular Coupling Method. J. Am. Chem. Soc. 2005, 127, 484-485.
16. Huang, F.; Zakharov, L. N.; Rheingold, A. L.; Ashraf-Khorassani, M.; Gibson, H. W.* Synthesis of a Symmetric Cylindrical Bis(crown ether) Host and Its Complexation with Paraquat. J. Org. Chem. 2005, 70, 809-813.
17. Gibson, H. W.;* Ge, Z.; Huang, F.; Jones, J. W.; Lefebvre, H.; Vergne, M. J.; Hercules, D. M. Syntheses and Model Complexation Studies of Well-Defined Crown Terminated Polymers. Macromolecules 2005, 38, 2626-2637.
18. Huang, F.; Guzei, I. A.; Jones, J. W.; Gibson, H. W.* Remarkably Improved Complexation of a Bisparaquat by Formation of a Pseudocryptand-Based [3]Pseudorotaxane. Chem. Commun. 2005, 1693-1695.
19. Huang, F.; Gibson, H. W.* A Supramolecular Poly[3]pseudorotaxane from Self-Assembly of a Homoditopic Cylindrical Bis(crown ether) Host and a Bisparaquat Derivative. Chem. Commun. 2005, 1696-1698.
20. Huang, F.; Switek, K. A.; Zakharov, L. N.; Fronczek, F. R.; Slebodnick, C.; Lam, M.; Golen, J. A.; Bryant, W. S.; Mason, P.; Rheingold, A. L.; Ashraf-Khorassani, M.; Gibson, H. W.* Bis(m-phenylene)-32-crown-10-Based Cryptands, Powerful Hosts for Paraquat Derivatives. J. Org. Chem. 2005, 70, 3231-3241.
21. Huang, F.; Lam, M.; Mahan, E. J.; Rheingold, A. L.; Gibson, H. W.* Promotion of Host Folding during the Formation of a Taco Complex. Chem. Commun. 2005, 3268-3270.
22. Huang, F.; Switek, K. A.; Gibson, H. W.* pH-Controlled Assembly and Disassembly of a Cryptand/Paraquat [2]Pseudorotaxane. Chem. Commun. 2005, 3655-3657.
23. Huang, F.; Gibson, H. W.* Polypseudorotaxanes and Polyrotaxanes. Prog. Polym. Sci. 2005, 30, 982-1018.
24. Huang, F.; Slebodnick, C.; Ratliff, A.; Gibson, H. W.* A Bis(m-phenylene)-32-crown-10/Monopyridinium [2]Pseudorotaxane. Tetrahedron Lett. 2005, 46, 6019-6022.
25. Huang, F.; Fronczek, F. R.; Ashraf-Khorassani, M.; Gibson, H. W.* Slow-Exchange C3-Symmetric Cryptand/Trispyridinium Inclusion Complexes Containing Nonlinear Guests: A New Type of Threaded Structure. Tetrahedron Lett. 2005, 46, 6765-6769.
26. Huang, F.; Slebodnick, C.; Rheingold, A. L.; Switek, K. A.; Gibson, H. W.* [2]Pseudorotaxanes Based on the Cryptand/Monopyridinium Recognition Motif. Tetrahedron 2005, 61, 10242-10253.
27. Huang, F.;* Slebodnick, C.; Switek, K. A.; Gibson, H. W.* Bis(m-phenylene)-32-Crown-10-Based Cryptand/Diquat Inclusion [2]Complexes. Chem. Commun. 2006, 1929-1931.
28. Huang, F.;* Yang, H.-B.; Das, N.; Maran, U.; Arif, A. M.; Gibson, H. W.; Stang, P. J. Incorporating a Flexible Crown Ether into Neutral Discrete Self-Assemblies Driven by Metal-Coordination. J. Org. Chem. 2006, 71, 6623-6625.
29. Yang, H.-B.; Das, N.; Huang, F.; Hawkridge, A. M.; Muddiman, D. C.; Stang, P. J.* Molecular Architecture via Coordination: Self-Assembly of Nanoscale Hexagonal Metallodendrimers with Designed Building Blocks. J. Am. Chem. Soc. 2006, 128, 10014-10015.
30. Yang, H.-B.; Das, N.; Huang, F.; Hawkridge, A. M.; Diaz, D. D.; Arif, A. M.; Finn, M. G.; Muddiman, D. C.; Stang, P. J.* Incorporation of 2,6-Di(4,4'-dipyridyl)-9-thiabicyclo[3.3.1]nonane into Discrete 2D Supramolecules via Coordination-Driven Self-Assembly. J. Org. Chem. 2006, 71, 6644-6647.
31. Huang, F.;* Gantzel, P.; Nagvekar, D. S.; Rheingold, A. L.; Gibson, H. W.* Taco Grande: a Dumbbell Bis(crown ether)/Paraquat [3](Taco Complex). Tetrahedron Lett. 2006, 47, 7841-7844.
32. Huang, F.;* Slebodnick, C.; Switek, K. A.; Gibson, H. W.* Inclusion [2]Complexes Based on the Cryptand/Diquat Recognition Motif. Tetrahedron 2007, 63, 2829-2839.
33. Huang, F.;* Slebodnick, C.; Mahan, E. J.; Gibson, H. W.* [3]Pseudorotaxanes Based on the Cryptand/Monopyridinium Salt Recognition Motif. Tetrahedron 2007, 63, 2875-2881.
34. Huang, F.;* Nagvekar, D. S.; Zhou, X.; Gibson, H. W.* Formation of a Linear Supramolecular Polymer by Self-Assembly of Two Homoditopic Monomers Based on the Bis(m-phenylene)-32-crown-10/Paraquat Recognition Motif. Macromolecules 2007, 40, 3561-3567.
35. Huang, F.; Pederson, A. M.; Gibson, H. W.* Polyrotaxanes. In Physical Properties of Polymers Handbook; Mark, J. E. Ed.; Springer-Verlag: New York, 2007; 693.
36. Huang, F.;* Jones, J. W.; Gibson, H. W.* Competitive Interactions of Two Ion-Paired Salts with a Neutral Host to Form Two Non-Ion-Paired Complexes. J. Org. Chem. 2007, 72, 6573-6576.
37. Zhang, X.; Zhai, C.; Li, N.; Liu, M.; Li, S.; Zhu, K.; Zhang, J.; Huang, F.;* Gibson, H. W. Host Size Effect in the Complexation of Two Bis(m-phenylene)-32-crown-10-Based Cryptands with a Diazapyrenium Salt. Tetrahedron Lett. 2007, 48, 7537-7541.
38. Zhang, J.; Huang, F.;* Li, N.; Wang, H.; Gibson, H. W.;* Gantzel, P.; Rheingold, A. L. Paraquat Substituent Effect on Complexation with a Dibenzo-24-crown-8-Based Cryptand. J. Org. Chem. 2007, 72, 8935-8938.
39. Zhang, C.; Li, S.; Zhang, J.; Zhu, K.; Li, N.; Huang, F.* Benzo-21-crown-7/Dialkylammonium Salt [2]Pseudorotaxane- and [2]Rotaxane-Type Threaded Structures. Org. Lett. 2007, 9, 5553-5556.
40. Li, S.; Liu, M.; Zhang, J.; Zheng, B.; Zhang, C.; Wen, X.; Li, N.; Huang, F.* High-yield Preparation of [2]Rotaxanes Based on the Bis(m-phenylene)-32-Crown-10-Based Cryptand/Paraquat Derivative Recognition Motif. Org. Biomol. Chem. 2008, 6, 2103-2107.
41. Zhang, J.; Zhai, C.; Wang, F.; Zhang, C.; Li, S.; Zhang, M.; Li, N.; Huang, F.* A Bis(m-phenylene)-32-crown-10-Based Fluorescence Chemosensor for Paraquat and Diquat. Tetrahedron Lett. 2008, 49, 5009-5012.
42. Pederson, A. M.-P.; Vetor, R. C.; Rouser, M. A.; Huang, F.; Slebodnick, C.; Schoonover, D. V.; Gibson, H. W.* A New Functional Bis(m-phenylene)-32-crown-10-Based Cryptand Host for Paraquats. J. Org. Chem. 2008, 73, 5570-5573.
43. He, C.; Shi, Z.; Zhou, Q.; Li, S.; Li, N.; Huang, F.* Syntheses of cis- and trans-Dibenzo-30-crown-10 Derivatives via Regioselective Routes and Their Complexations with Paraquat and Diquat. J. Org. Chem. 2008, 73, 5872-5880.
44. Wang, F.; Han, C.; He, C.; Zhou, Q.; Zhang, J.; Wang, C.; Li, N.; Huang, F.* Self-Sorting Organization of Two Heteroditopic Monomers to Supramolecular Alternating Copolymers. J. Am. Chem. Soc. 2008, 130, 11254-11255 (Highlighted by Vicki, C. Molecular self-assembly: Sort it out! Nature China 2008, 20 August).
45. Zhang, C.; Zhu, K.; Li, S.; Zhang, J.; Wang, F.; Liu, M.; Li, N.; Huang, F.* Binding of secondary dialkylammonium salts by pyrido-21-crown-7. Tetrahedron Lett. 2008, 49, 6917-6920.
46. Zhu, K.; Zhang, M.; Wang, F.; Li, N.; Li, S.; Huang, F.* Improved Complexation between Dibenzo-24-crown-8 Derivatives and Dibenzylammonium Salts by Ion-Pair Recognition. New J. Chem. 2008, 32, 1827-1830.
47. Li, S.; Liu, M.; Zhang, J.; Zheng, B.; Wen, X.; Li, N.; Huang, F.* Preparation of Bis(m-phenylene)-32-crown-10-Based Cryptand/Bisparaquat [3]Rotaxanes with High Efficiency. Eur. J. Org. Chem. 2008, 6128-6133.
48. Zhou, Q.; He, C.; Zhai, C.; Huang, F.* Templated Syntheses of Molecules with Mechanically Interlocked Structures. Huaxue Tongbao 2008, 71, 809-815.
49. Wang, F.; Zhou, Q.; Zhu, K.; Li, S.; Wang, C.; Liu, M.; Li, N.; Fronczek, F. R.; Huang, F.* Efficient Syntheses of Bis(m-phenylene)-26-crown-8-Based Cryptand/Paraquat [2]Rotaxanes by Immediate Solvent Evaporation Method. Tetrahedron 2009, 65, 1488-1494.
50. Li, S.; Zhu, K.; Zheng, B.; Wen, X.; Li, N.; Huang, F.* A Bis(m-phenylene)-32-crown-10/Paraquat [2]Rotaxane. Eur. J. Org. Chem. 2009, 1053-1057.
51. Zhu, K.; Li, S.; Wang, F.; Huang, F.* Anion-Controlled Ion-Pair Recognition of Paraquat by a Bis(m-phenylene)-32-crown-10 Derivative Heteroditopic Host. J. Org. Chem. 2009, 74, 1322-1328.
52. Liu, M.; Li, S.; Zhang, M.; Zhou, Q.; Wang, F.; Hu, M.; Fronczek, F. R.; Li, N.; Huang, F.* Three-Dimensional Bis(m-phenylene)-32-crown-10-Based Cryptand/Paraquat Catenanes. Org. Biomol. Chem. 2009, 7, 1288-1291.
53. Ge, Z.; Hu, J.; Huang, F.;* Liu, S.* Responsive Supramolecular Gels Constructed by Crown Ether Based Molecular Recognition. Angew. Chem. 2009, 121, 1830-1834; Angew. Chem. Int. Ed. 2009, 48, 1798-1802.
54. Zhu, K.; He, J.; Li, S.; Liu, M.; Wang, F.; Zhang, M.; Abliz, Z.; Yang, H.; Li, N.; Huang, F.* Synthesis of Bis(m-phenylene)-32-crown-10-Based Discrete Rhomboids Driven by Metal-Coordination and Complexation with Paraquat. J. Org. Chem. 2009, 74, 3905-3912.
55. Wang, F.; Zheng, B.; Zhu, K.; Zhou, Q.; Zhai, C.; Li, S.; Li, N.; Huang, F.* Formation of Linear Main-Chain Polypseudorotaxanes with Supramolecular Polymer Backbones via Two Self-Sorting Host-Guest Recognition Motifs. Chem. Commun. 2009, 4375-4377.
56. Gibson, H. W.;* Farcas, A.; Jones, J. W.; Ge, Z.; Huang, F.; Vergne, M.; Hercules, D. M. Supramacromolecular self-assembly: Chain extension, star and block polymers via pseudorotaxane formation from well-defined end-functionalized polymers. J. Polym. Sci., Part A: Polym. Chem. 2009, 47, 3518-3543.
57. Li, S.; Liu, M.; Zheng, B.; Zhu, K.; Wang, F.; Li, N.; Zhao, X.; Huang, F.* Taco Complex Templated Syntheses of a Cryptand/Paraquat [2]Rotaxane and [2]Catenane by Olefin Metathesis. Org. Lett. 2009, 11, 3350-3353.
58. Li, S.; Huang, F.;* Slebodnick, C.; Ashraf-Khorassani, M.; Gibson, H. W.* Complexes of Diquat with Dibenzo-24-Crown-8. Chin. J. Chem. 2009, 27, 1777-1781.
59. Wang, F.; Zhang, J.; Ding, X.; Dong, S.; Liu, M.; Zheng, B.; Li, S.; Wu, L.; Yu, Y.; Gibson, H. W.; Huang, F.* Metal-Coordination-Mediated Reversible Conversion between Linear and Crosslinked Supramolecular Polymers. Angew. Chem. 2010, 122, 1108-1112; Angew. Chem. Int. Ed. 2010, 49, 1090-1094 (Highlighted by Swager, T. M. Reversible Conversion between Linear and Cross-Linked Supramolecular Polymers. Synfacts 2010, 0542-0542).
60. Liu, M.; Li, S.; Hu, M.; Wang, F.; Huang, F.* Selectivity Algorithm for the Formation of Two Cryptand/Paraquat Catenanes. Org. Lett. 2010, 12, 760-763.
61. Li, S.;* Zheng, B.; Huang, F.; Zakharov, L. N.; Slebodnick, C.; Rheingold, A. L.; Gibson, H. W. A new cryptand/paraquat [2]pseudorotaxane. Sci. China Ser. B-Chem. 2010, 53, 858-862.
62. Zhu, K.; Wu, L.; Yan, X.; Zheng, B.; Zhang, M.; Huang, F.* Anion Assisted Complexation of Paraquat by Bis(m-phenylene)-32-crown-10-Based Cryptands. Chem. Eur. J. 2010, 16, 6088-6098.
63. Liu, M.; Yan, X.; Hu, M.; Chen, X.; Zhang, M.; Zheng, B.; Hu, X.; Shao, S.; Huang, F.* Photoresponsive Host-Guest Systems Based on a New Azobenzene-Containing Crytpand. Org. Lett. 2010, 12, 2558-2661.
64. Wu, L.; Liu, M.; Chen, X.; Li, S.; Huang, F.* Negatively Charged Crown Ethers for Binding Paraquat in Water. Sci. China Ser. B-Chem. 2010, 53, 1074-1080.
65. Zhang, Z.; Xia, B.; Han, C.; Yu, Y.; Huang, F.* Syntheses of Copillar[5]arenes from Co-Oligomerization of Different Monomers. Org. Lett. 2010, 12, 3285-3287 (Abstracted by ChemInform 2010, 41, DOI: 10.1002/chin.201041049).
66. Li, S.; Zheng, B.; Chen, J.; Dong, S.; Ma, Z.; Huang, F.;* Gibson, H. W. A Hyperbranched, Rotaxane-Type Mechanically Interlocked Polymer. J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 4067-4073 (Highlighted by Swager, T. M. Mechanically Interlocked Polymers. Synfacts 2010, 1239-1239).
67. Zhang, M.; Luo, Y.; Zheng, B.; Xia, B.; Huang, F.* Improved and Controlled Complexation of Paraquat Derivatives by the Formation of A Bis(m-phenylene)-26-crown-8-Based Lariat Ether. Eur. J. Org. Chem. 2010, 5543-5547.
68. Zhang, M.; Luo, Y.; Zheng, B.; Yan, X.; Fronczek, F. R.; Huang, F.* Improved Pseudorotaxane and Catenane Formation from a Derivative of Bis(m-phenylene)-32-crown-10. Eur. J. Org. Chem. 2010, 6798-6803.
69. Zhang, M.; Zheng, B.; Xia, B.; Zhu, K.; Wu, C.; Huang, F.* Synthesis of A Bis(1,2,3-phenylene) Cryptand and Its Dual-Responsive Binding to Paraquat and Diquat. Eur. J. Org. Chem. 2010, 6804-6809.
70. Zhang, M.; Zhu, K.; Huang, F.* Improved Complexation of Paraquat Derivatives by the Formation of Crown Ether-Based Cryptands. Chem. Commun. 2010, 46, 8131-8141 (Feature Article).
71. Han, C.; Ma, F.; Zhang, Z.; Xia, B.; Yu, Y.; Huang, F.* DIBPillar[n]arenes (n = 5, 6): Syntheses, X-Ray Crystal Structures, and Complexation with n-Octyltriethyl Ammonium Hexafluorophosphate. Org. Lett. 2010, 12, 4360-4363.
72. Zhang, Z.; Luo, Y.; Chen, J.; Dong, S.; Yu, Y.; Ma, Z.; Huang, F.* Formation of Linear Supramolecular Polymers That Is Driven by the C-H•••π Interactions in Solution and in the Solid State. Angew. Chem. Int. Ed. 2011, 50, 1397-1401.
73. Dong, S.; Luo, Y.; Yan, X.; Zheng, B.; Ding, X.; Yu, Y.; Ma, Z.; Zhao, Q.; Huang, F.* A Dual-Responsive Supramolecular Polymer Gel Formed by Crown Ether Based Molecular Recognition. Angew. Chem. Int. Ed. 2011, 50, 1905-1909.
74. Zhang, Z.; Luo, Y.; Xia, B.; Han, C.; Yu, Y.; Chen, X.; Huang, F.* Four Constitutional Isomers of BMpillar[5]arene: Synthesis, Crystal Structures and Complexation with n-Octyltrimethyl Ammonium Hexafluorophosphate. Chem. Commun. 2011, 47, 2417-2419.
75. Niu, Z.; Huang, F.; Gibson, H. W.* Supramolecular AA BB Type Linear Polymers with Relatively High Molecular Weights via the Self-Organization of Bis(meta-phenylene)-32-Crown-10 Cryptands and a Bisparaquat Derivative. J. Am. Chem. Soc. 2011, 133, 2836-2839.
76. Niu, Z.; Slebodnick, C.; Bonrad, K.; Huang, F.; Gibson, H. W.* The First [2]Pseudorotaxane and the First Pseudocryptand-Type Poly[2]pseudorotaxane Based on Bis(meta-phenylene)-32-Crown-10 and Paraquat Derivatives. Org. Lett. 2011, 13, 2872-2875.
77. Yan, X.; Zhou, M.; Chen, J.; Chi, X.; Dong, S.; Zhang, M.; Ding, X.; Yu, Y.; Shao, S.; Huang, F.* Supramolecular Polymer Nanofibers via Electrospinning of a Heteroditopic Monomer. Chem. Commun. 2011, 47, 7086-7088.
78. Yan, X.; Zhang, M.; Wei, P.; Zheng, B.; Chi, X.; Ji, X.; Huang, F.* pH-Responsive assembly and Disassembly of a Supramolecular Cryptand-based Pseudorotaxane Driven by p-p Stacking Interaction. Chem. Commun. 2011, 47, 9840-9842.
79. Xia, B.; He, J.; Zeper, A.; Yu, Y.; Huang, F.* Synthesis of a Pillar[5]arene Dimer by Co-oligomerization and Its Complexation with n-Octyltrimethyl Ammonium Hexafluorophosphate. Tetrahedron Lett. 2011, 52, 4433-4436.
80. Ma, Y.; Zhang, Z.; Ji, X.; Han, C.; He, J.; Zeper, A.; Chen, W.; Huang, F.* Preparation of Pillar[n]arenes (n = 5 or 6) by Cyclooligomerization of 2,5-Dialkoxybenzyl Alcohols or 2,5-Dialkoxybenzyl Bromides. Eur. J. Org. Chem. 2011, 5331-5335.
81. Zhang, M.; Zheng, B.; Huang, F.* Synthesis of a Four-armed Cage Molecule and Its pH-Controlled Complexation with Paraquat. Chem. Commun. 2011, 47, 10103-10105.
82. Zhang, Z.; Yu, G.; Han, C.; Liu, J.; Ding, X.; Yu, Y.; Huang, F.* Formation of a Cyclic Dimer Containing Two Mirror Image Monomers in the Solid State Controlled by van der Waals Forces. Org. Lett. 2011, 13, 4818-4821.
83. Ma, Y.; Ji, X.; Xiang, F.; Chi, X.; Han, C.; He, J.; Abliz, Z.; Chen, W.; Huang, F.* A Cationic Water-Soluble Pillar[5]arene: Synthesis and Host-Guest Complexation with Sodium 1-Octanesulfonate. Chem. Commun. 2011, 47, 12340-12342.
84. Yan, X.; Wei, P.; Zhang, M.; Chi, X.; Liu, J.; Huang, F.* [2]Pseudorotaxanes Based on the Recognition of Cryptands to Vinylogous Viologens. Org. Lett. 2011, 13, 6370-6373.
85. Zhang, M.; Li, S.; Dong, S.; Chen, J.; Zheng, B.; Huang, F.* Preparation of a Daisy Chain via Threading-Followed-by-Polymerization. Macromolecules 2011, 44, 9629-9634.
86. Chang, K.; Chen, W.;* Ma, L.; Li, H.; Li, H.; Huang, F.; Xu, Z.; Zhang, Q.; Lee, J.-Y. Graphene-like MoS2/Amorphous Carbon Composites with High Capacity and Excellent Stability as Anode Materials for Lithium Ion Batteries. J. Mater. Chem. 2011, 21, 6251-6257.
87. Niu, Z.; Slebodnick, C.; Huang, F.; Azurmendi, H.; Gibson, H. W.* An Acid–Base Adjustable Pseudocryptand-type [2]Pseudorotaxane Based on a Bis(meta-phenylene)-32-Crown-10 Derivative and Paraquat. Tetrahedron Lett. 2011, 52, 6379-6382.
88. Chen, J.; Yan, X.; Zhao, Q.; Li, L.;* Huang, F.* Adjustable Supramolecular Polymer Microstructures Fabricated by the Breath-figure Method. Polym. Chem. 2012, 3, 458-462.
89. Yan, X.; Xu, D.; Chi, X.; Chen, J.; Dong, S.; Ding, X.; Yu, Y.; Huang, F.* A Multiresponsive, Shape-Persistent, and Elastic Supramolecular Polymer Network Gel Constructed by Orthogonal Self-Assembly. Adv. Mater. 2012, 24, 362-369.
90. Zheng, B.; Wang, F.; Dong, S.; Huang, F.* Supramolecular Polymers Constructed by Crown Ether-Based Molecular Recognition. Chem. Soc. Rev. 2012, 41, 1621-1636.
91. Zheng, B.; Zhang, M.; Dong, S.; Liu, J.; Huang, F.* A Benzo-21-Crown-7/Secondary Ammonium Salt [c2]Daisy Chain. Org. Lett. 2012, 14, 306-309.
92. Yu, G.; Zhang, Z.; Han, C.; Xue, M.; Zhou, Q.;* Huang, F.* A Non-symmetric Pillar[5]arene-Based Selective Anion Receptor for Fluoride. Chem. Commun. 2012, 48, 2958-2960.
93. Dong, S.; Yan, X.; Zheng, B.; Chen, J.; Ding, X.; Yu, Y.; Xu, D.; Zhang, M.; Huang, F.* A Supramolecular Polymer Blend Containing Two Different Supramolecular Polymers via Self-Sorting Organization of Two Heteroditopic Monomers. Chem. Eur. J. 2012, 18, 4195-4199.
94. Ji, X.; Zhu, K.; Yan, X.; Ma, Y.; Li, J.; Hu, B.; Yu, Y.; Huang, F.* pH-Responsive Supramolecular Polymerization in Aqueous Media Driven by Electrostatic Attraction-Enhanced Crown Ether-Based Molecular Recognition. Macromol. Rapid Commun. 2012, 33, 1197-1202.
95. Ma, Y.; Chi, X.; Yan, X.; Liu, J.; Yao, Y.; Chen, W.; Hou, J.-L.;* Huang, F.* per-Hydroxylated Pillar[6]arene: Synthesis, X-ray Crystal Structure and Host-Guest Complexation. Org. Lett. 2012, 14, 1532-1535.
96. Han, C.; Yu, G.; Zheng, B.; Huang, F.* Complexation between Pillar[5]arenes and a Secondary Ammonium Salt. Org. Lett. 2012, 14, 1712-1715.
97. Yan, X.; Wei, P.; Xia, B.; Huang, F.;* Zhou, Q.* Pseudorotaxanes from Self-Assembly of Two Crown Ether-Based Cryptands and a 1,2-Bis(pyridinium)ethane Derivative. Chem. Commun. 2012, 48, 4968-4970.
98. Xue, M.; Yang, Y.; Chi, X.; Zhang, Z.; Huang, F.* Pillararenes, A New Class of Macrocycles for Supramolecular Chemistry. Acc. Chem. Res. 2012, 45, 1294-1308.
99. Dong, S.; Zheng, B.; Xu, D.; Yan, X.; Zhang, M.; Huang, F.* A Crown Ether Appended Super Gelator with Multiple Stimulus Responsiveness. Adv. Mater. 2012, 24, 3191-3195.
100. Dong, S.; Han, C.; Zheng, B.; Zhang, M.; Huang, F.* Preparation of Two New [2]Rotaxanes Based on the Pillar[5]arene/Alkane Recognition Motif. Tetrahedron. Lett. 2012, 53, 3668-3671.
101. Yao, Y.; Xue, M.; Chi, X.; Ma, Y.; He, J.; Abliz, Z.; Huang, F.* A New Water-Soluble Pillar[5]arene: Synthesis and Application in the Preparation of Gold Nanoparticles. Chem. Commun. 2012, 48, 6505-6507.
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