余达刚博士，男，1986年9月出生于江西奉新。
学习经历
2003.09—2007.07 四川大学化学学院读本科，导师：冯小明教授，袁立华教授
2007.09—2012.07北京大学化学与分子工程学院有机化学专业攻读博士学位，导师：施章杰教授
工作经历
2012.10—2014.12 德国明斯特大学进行博士后研究，洪堡学者，导师： Prof. Frank Glorius
2015.01至今 四川大学化学学院从事教学和科研，教授, 博士生导师
学术兼职
Chem. Synth.副主编
Chin. Chem. Lett.副主编
《化学学报》、《有机化学》、Asian J. Org. Chem.编委
Sci. Bull. 和《科学通报》、Sci. China Chem.和《中国科学-化学》、Chin. J. Catal.青年编委
Tetrahedron Green Chem, Advisory Board Member
中国化学会二氧化碳化学专业委员会委员
中国化学会光化学专业委员会委员
中国化学会催化委员会均相催化专业委员会委员
中国化学会青年化学工作者委员会第三届委员
中国感光学会第一届青年理事会理事
主要研究方向
绿色有机合成化学（二氧化碳利用、可见光催化、电化学）
过渡金属催化方法学（铜、铁等廉价金属催化）
功能分子构建新方法研究（重要杂环、羧酸合成）
诚招副研究员、博后、研究助理、硕博生以及交流生
主要工作业绩
二氧化碳（CO2）作为空气中的重要组分，也是广泛存在、廉价易得、无毒、稳定、可再生循环使用的“碳一”（C1）资源。由于CO2在热力学和动力学方面有较高的稳定性，反应活性较低，CO2活化具有巨大的挑战。2015年余达刚博士独立建组以来，坚持围绕CO2活化与转化的基本科学问题开展独特研究，发展了CO2高效活化与选择性转化的新理念、新策略和新反应，具体如下：
针对碳氢键氧化羰基化反应中存在的问题（需要使用剧毒的CO和当量的氧化剂），我们首次提出“CO2 = CO + [O]”理念，利用CO2代替CO和氧化剂参与碳氢键羰基化反应，发展了近十类重要含羰基杂环类化合物的高效合成方法，提出了新反应机制，不仅变废为宝，还降低成本，提高安全性，具有较强的实用性；基于过渡金属催化和可见光催化策略，我们发展了“自由基型CO2转化”模式，一方面通过调控自由基参与不饱和烃转化反应的选择性，在室温常压下实现了噁唑啉酮和多种类型羧酸的高效制备，另一方面基于“可见光促进单电子活化”策略和电还原策略，通过单电子还原CO2或底物形成自由基负离子，实现了具有独特区域选择性的烯烃羧基化反应以及氮杂芳烃区域选择性可调控的羧基化反应；基于极性翻转策略，我们通过惰性化学键（如碳氟键、碳氮键和碳氧键）的选择性断裂实现了CO2参与的羧基化反应；此外，我们实现了铜或镍催化CO2参与的不饱和烃的碳碳成键反应，取得了优秀的对映选择性、化学选择性、区域选择性和Z/E选择性，高效构建了具有手性（季碳）中心的高苄醇、高烯丙醇和羧酸。这些工作实现了CO2的变废为宝和高附加值产品的精准合成，为研究CO2活化的本质和规律提供了新的实验基础和理论模型，为促进我国CO2化学研究起了积极的作用。
独立工作以来，余达刚博士以通讯作者身份在Nature、Nature Catal.、Nature Synth.、Acc. Chem. Res.、Chem.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Nature Commun.、Sci. Bull.、Chin. J. Catal.、CCS Chem.、Sci. China Chem.、Chin. Chem. Lett.和Chin. J. Chem.等学术刊物上发表学术论文110余篇，其中有多篇论文成为相应期刊封面、扉页文章、VIP和当月下载量前列的文章，多篇被国家自然科学基金委、科学网、中国网、ChemistryViews、Synform、Synfacts、Organic Chemistry Portal、OPR&D和《有机化学》等作为亮点介绍。此外，在国内外学术会议、大学和企业做了130余次报告，并作为共同客座编辑组织了Chin. J. Chem.、Green Chem.和Chin. J. Catal.等期刊的“二氧化碳化学”专辑。
主要奖励和荣誉
2025年度新时代青年先锋奖
2025年光化学与光催化青年科学家奖
2025年 “Chemical Society Reviews” Pioneering Investigators
2025年 “Chemical Communications” Pioneering Investigators
2025年中国青年科技工作者协会会员
2025年四川大学“优秀共产党员”
爱思唯尔 (Elsevier) 2024“中国高被引学者”
2024年第十八届中国青年科技奖
2024年四川大学“十佳”学生集体
2024年四川大学中长期“双高计划”
2023年中国化学会-英国皇家化学会青年化学奖
2023年度四川十大科学进展
爱思唯尔 (Elsevier) 2023“中国高被引学者”
2023年四川大学十大基础研究进展奖
2023年四川大学优秀本科毕业论文指导教师
2022年国家自然科学基金委杰出青年基金
2022 Kyoto Rising-Star Lectureship Award
2022年四川省学术和技术带头人
2021年中国催化新秀奖
2021年川渝科学技术大会优秀学术论文一等奖
2021年四川大学“先进个人”、四川大学百人计划A
2021年大学生创新创业教育优秀指导教师、四川大学拔尖创新人才优秀指导教师、四川大学优秀社团指导教师
2020年“Science China Chemistry” Emerging Investigator
2020年“Chemical Communications” Emerging Investigator
2020年 四川大学“中青年科技领军人才培育计划”
2019年四川大学优秀本科毕业论文指导教师、四川大学拔尖创新人才培养优秀指导教师、四川大学大学生创新创业教育优秀指导教师、四川大学课堂教学质量优秀奖
2018年中国化学会青年化学奖
2018年国家自然科学基金委优秀青年基金
2018年霍英东青年教师基金
2018年四川大学优秀教师、四川大学优秀青年科技人才奖
2017 ACP Lectureship Awards to Japan
2017 Thieme Chemistry Journal Award
2017年四川大学优秀本科毕业论文指导教师、四川大学拔尖创新人才优秀指导教师、四川大学大学生创新创业教育优秀指导教师
2016年“Organic Chemistry Frontiers” Emerging Investigator
2016年四川大学青年科技人才奖、四川大学优秀本科毕业论文指导教师
2014年海外高层次人才引进计划青年项目
2013-2014年德国洪堡奖学金
2013年Reaxys PhD Prize (Finalist)
代表性成果 （获奖成果、专著、论文、专利）
1.X.-L. Hu,† L.-L. Liao,† J.-C. Xu,† J.-W. Yang, J.-Y. Wu, S. Zhang, S.-C. Wang, J.-P. Yue, Y. Jiang, G.-M. Cao, L, Song,* J.-H. Ye, D.-G. Yu*, Visible-Light-Driven α-C(sp3)−H Carboxylation of Primary Benzylamines with CO2 to Access α-Amino Acids. Angew. Chem. Int. Ed. 2025, 64, e202515737. († Equal contribution. Highlighted by化学深耕堂、雁城方法学、研之成理、X-Mol、CBG)
2.W. Wang,† S.-S. Yan,† Y. Liu, J.-S. Zhu, J.-W. Yang, J.-C. Xu, Y.-Y. Tao, J.-C. Li, L. Song, J.-H. Ye,* D.-G. Yu*, Photocatalytic 1,2-Dicarboxylation of Unactivated Alkynes with CO2. J. Am. Chem. Soc. 2025, 147, 23715–23723. († Equal contribution. Highlighted by Synfacts 2025, 21, 918; 化学深耕堂、化学加、CBG、催化计、邃瞳科学云、微算云平台、半池清月)
3.Chao Li,† X.-W. Chen,† L.-L. Liao,† Y.-Y. Gui*, J.-W. Yang, S. Zhang, J.-P. Yue, X. Zhou*, J.-H. Ye, Y. Lan, D.-G. Yu*, Nickel-Catalyzed Atroposelective Carbo-Carboxylation of Alkynes with CO2: En Route to Axially Chiral Carboxylic Acids. Angew. Chem. Int. Ed. 2025, 64, e202413305. († Equal contribution. Hot Paper. Highlighted by化学深耕堂、X-Mol、CBG、有机文献速览、微算云平台)
4.J.-C. Xu,† J.-P. Yue,† M. Pan, Y.-C. Chen, W. Wang, X. Zhou, W. Zhang*, J.-H. Ye, D.-G. Yu*, Metallaphotoredox-catalyzed alkynylcarboxylation of alkenes with CO2 and alkynes for expedient access to β-alkynyl acids. Nat. Commun. 2025, 16, 1850. († Equal contribution. Highlighted by Synfacts 2025, 21, 594;有机文献速览、化学身边学、邃瞳科学云)
5.G.-M. Cao,† S.-S. Yan,† L. Song,* Y.-X. Jiang, T.-Y Gao, Z. Chen, W. Zhang,* J.-H. Ye, D.-G. Yu*, Navigating the functionalization of unactivated alkenes via visible-light photocatalysis. Chem. Soc. Rev. 2025, 54, 6726–6806. († Equal contribution.)
6.H.-Y. Huang, M. Xie, S.-Q. Wang, Y.-T. Huang, Y.-H. Luo, D.-G. Yu, Z.-Z. Cai*, J.-B. Zhu*, Ultratough Thermoplastic Elastomers Based on Chemically Recyclable Cycloalkyl-Substituted Polyhydroxyalkanoates. J. Am. Chem. Soc. 2025, 147, 7788.
7.X. Li, W. Yang, J.-P. Yue, J. Li*, S. Shen, R. Chen, J. Wang, H. Dan, D.-G. Yu, F. Dong*, Photocatalytic C-N coupling from stable and transient intermediates for gram-scale acetamide synthesis. Nat. Commun. 2025, 16, 3590.
8.H. Zhao,† Y.-C. Chen,† X.-T. Li, D.-W. Sun, L. Ye, J.-B. Zhu, J.-H. Ye, X.-H. Xiong,* Z.-S. Wu, D.-G. Yu*, Electroreductive Carboxylation of Graphite with CO2 for Lithium-Sulfur Battery with Boosting Performance. Chem. Commun. 2025, 61, 15838–15841. († Equal contribution. ChemComm Pioneering Investigators themed collection)
9.J.-W. Yang,† C.-K. Ran,† W.-J. Zhu, Y. Jiang, S.-S. Yan,* J.-H. Ye, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Carboxylation of Benzylic C(sp3)─O Bonds in Ethers with CO2. J. Org. Chem. 2025, 90, 8406–8412. († Equal contribution.)
10.Q. Zhou, C. Zhang, H.-L. Luo, C.-X. Nie, C. Hu, J.-H. Ye, Z. Su*, L.-L. Liao*, D.-G. Yu*, Carbon–metal bond homolysis-recombination enabling enantioconvergent carboxylation with CO2: A theoretical study. Chin. Chem. Lett. 2025, 36, 111429.
11.Y.-Y. Jiang,† Z. Chen,† Y.-X. Jiang, W.-J. Zhu, J.-C. Xu, J.-H. Ye, W. Zhang*, D.-G. Yu*, Visible-light-driven thiolate-catalyzed carbo-carboxylation of alkenes with CO2: facile synthesis of oxindole-3-acetic acids derivatives. Chin. J. Chem. 2025, 43, 2341–2346. († Equal contribution. Highlighted by CJC、CBG)
12.W.-C. Li, J. Ming,* D.-G. Yu*, Stereoselective C(sp3)–H alkylation of saturated heterocycles with olefins. Sci. China Chem. 2025, 68, 3912–3914. (Highlight)
13.Z. Guan,† L.-L. Liao,† Y.-Y. Gui, C. Zhang, X. Zhou, D.-G. Yu*, H. Xiang*, A Computer-Based Exercise on Racemization Mechanism and Energy Barrier of Axially Chiral Molecules. J. Chem. Educ. 2025, 102, 2398–2407.
14.L.-F. Dai,† Y.-X. Jiang,† D.-L. Yu, G.-Q. Sun, S.-S. Yan,* W. Zhang, J.-H. Ye, D.-G. Yu*, Photocatalytic Sequential Dimerization and Skeletal Rearrangement of Quinolines: Facile Synthesis of Indole-methylquinoline Hybrids. ACS Catal. 2025, 15, 7792−7799. († Equal contribution. Highlighted by化学深耕堂、CBG、研之成理、科研云资讯、科研留声机)
15.C. Li,† W. Zhang,† Y. Xu, Y. Su, T.-Y. Gao, J.-H. Ye, L. Song,* D.-G. Yu*, Carboxylation of C(sp2)−H bonds in quinolone derivatives with CO2: facile synthesis of quinolone carboxylic acids. Org. Chem. Front. 2025, 12, 4499–4505. († Equal contribution.)
16.Y.-X. Jiang, L.-L. Liao, J.-H. Ye*, D.-G. Yu*, Visible-Light-Driven Thiolate-Catalyzed Carboxylation of C(sp2)-H Bonds in Azines with CO2. Synlett 2025, 36, 1315-1321. (Invited Synpact paper)
17.Z. Zhang*, X.-L. Chen, X.-M. Xie, T.-Y. Gao, J. Qin, J.-J. Li, C. Feng, D.-G. Yu*, Iron-promoted carbonylation–rearrangement of α-aminoaryl-tethered alkylidenecyclopropanes with CO2: Facile synthesis of quinolinofurans. Chin. Chem. Lett. 2025, 36, 110056.
18.R. Ye,† J. Ming,† Q. Tao, T.-Y. Gao, J.-H. Ye, D.-G. Yu*, X. Zhou*, Transition-metal-free isofunctional reaction of α,β-unsaturated ketones/nitriles. Sci. China Chem. 2025, 68, 499-504. († Equal contribution. Highlighted by化学深耕堂、SCC)
19.G.-Q. Sun, L.-L. Liao, C.-K. Ran, J.-H. Ye, D.-G. Yu*, Recent Advances in Electrochemical Carboxylation with CO2. Acc. Chem. Res. 2024, 57, 2728-2745.(内封面，当月下载量前3)
20.J. Liu,† W. Wang,† L.-L. Liao,† W. Zhang, J.-P. Yue, Y. Liu, X.-W. Chen, J.-H. Ye*, D.-G. Yu*, Photo-Induced Carboxylation of C(sp2)−S Bonds in Aryl Thiols and Derivatives with CO2. Nat. Commun. 2024, 15, 10132. († Equal contribution. Highlighted by化学深耕堂、有趣的化学合成、化学加、CBG)
21.Y. Liu, G.-H. Xue, Z. He, J.-P. Yue, M. Pan, L. Song*, W. Zhang, J.-H. Ye, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Direct Carboxylation of Tertiary C(sp3)–H Bonds with CO2: Facile Synthesis of All-Carbon Quaternary Carboxylic Acids. J. Am. Chem. Soc. 2024, 146, 28350-28359. (当月下载量前13. Highlighted by Synfacts、化学深耕堂、X-Mol、CBG、催化计、催化开天地、催化加易点、岳麓化学、八桂化学、有机文献速览、微算云平台)
22.Q. Hu, B. Wei, M. Wang, M. Liu, X.-W. Chen, C.-K. Ran, G. Wang, Z. Chen, H. Li, J. Song, D.-G. Yu*, C. Guo*, Enantioselective nickel-electrocatalyzed reductive propargylic carboxylation with CO2. J. Am. Chem. Soc. 2024, 146, 14864–14874 (Highlighted by化学深耕堂、X-Mol、eChemStore)
23.X.-W. Chen, C. Li, Y.-Y. Gui,* J.-P. Yue, Q. Zhou, L.-L. Liao, J.-W. Yang, J.-H. Ye, D.-G. Yu*, Atropisomeric Carboxylic Acids Synthesis via Nickel-Catalyzed Enantioconvergent Carboxylation of Aza-biaryl Triflates with CO2. Angew. Chem. Int. Ed. 2024, 63, e202403401. (Highlighted by X-Mol、化学深耕堂、能源技术情报、科研留声机、CRS化学资讯、光电材料与器件)
24.Y.-Y. Gui,*,† X.-W. Chen,† X.-Y. Mo, J.-P. Yue, R. Yuan, Y. Liu, L.-L. Liao, J.-H. Ye, D.-G. Yu*, Cu-Catalyzed Asymmetric Dicarboxylation of 1,3-Dienes with CO2. J. Am. Chem. Soc. 2024, 146, 2919–2927. († Equal contribution. Highlighted by化学深耕堂、X-Mol、CBG)
25.Y.-X. Jiang,† L.-L. Liao,† T.-Y. Gao, W.-H. Xu, W. Zhang, L. Song, G.-Q. Sun, J.-H. Ye*, Y. Lan*, D.-G. Yu*, Visible-light-driven synthesis of N-heteroaromatic carboxylic acids by thiolate-catalysed carboxylation of C(sp⟡)-H bonds using CO2. Nat. Synth. 2024, 3, 394–405. († Equal contribution. Highlighted by化学加、化学深耕堂、催化计、化学宝库、有趣的化学合成、CBG)
26.B. Yu,† Y. Liu,† H.-Z. Xiao,† S.-R. Zhang, C.-K. Ran, L. Song, Y.-X. Jiang, C.-F. Li, J.-H. Ye,* D.-G. Yu*, Switchable Divergent Di- or Tricarboxylation of Allylic Alcohols with CO2. Chem 2024, 10, 938-951. (Highlighted by科学网、化学加、CBG、化学深耕堂、催化计、化学宝库、有趣的化学合成)
27.Y. Yan,† M. Pan,† J. Ming,* J.-P. Yue, X.-W. Chen, Y.-Y. Gui,* D.-G. Yu*, Transition-Metal-Catalyzed Construction of Axially Chiral Carbonyl Compounds. Eur. J. Org. Chem. 2024, 27, e202400995 († Equal contribution. Invited concept)
28.S.-R. Zhang,† J.-P. Yue,† L.-F. Wang, Y.-Y. Gui, W. Zhang,* D.-G. Yu, J.-H. Ye*, Dearomative hydroamination of heteroarenes catalyzed by the phenolate photocatalyst. Chem. Commun. 2024, 60, 13083-13086. († Equal contribution. ChemComm Emerging Investigators themed collection)
29.Y.-Y. Gui,† X.-W. Chen,† J.-P. Yue, D.-G. Yu*, Synergistic photoredox/palladium catalysis enables enantioconvergent carboxylation of racemic heterobiaryl (pseudo)halides with CO2. Chem. Synth. 2024, 4, 66. († Equal contribution. Highlight)
30.L. Li,† Z.-X. Yan,† C.-K. Ran,† Y. Liu, S. Zhang, T.-Y. Gao, L.-F. Dai, L.-L. Liao,* J.-H. Ye, D.-G. Yu*, Electro-reductive carboxylation of C─Cl bonds in unactivated alkyl chlorides and polyvinyl chloride with CO2. Chin. Chem. Lett. 2024, 35, 110104. († Equal contribution)
31.K.-G. Cao,† T.-Y. Gao,† L.-L. Liao,* C.-K. Ran, Y.-X. Jiang, W. Zhang, Q. Zhou, J.-H. Ye, Y. Lan, D.-G. Yu*, Photocatalytic carboxylation of styrenes with CO2 via C=C double bond cleavage. Chin. J. Catal. 2024, 56, 74-80. († Equal contribution)
32.C.-K. Ran, Q. Qu, Y.-Y. Tao, Y.-F. Chen, L.-L. Liao*, J.-H. Ye, D.-G. Yu*, Electro-Reductive Carboxylation of Acyclic C(sp3)─C(sp3) Bonds in Aromatic Hydrocarbons with CO2. Sci. China Chem. 2024, 67, 3366–3372.
33.X. Yao, Z. Wang*, D.-G. Yu*, Sustainable Electrosynthesis: Enantioselective Electrochemical Rh(III)/Chiral Carboxylic Acid-Catalyzed Oxidative C-H Cyclization Coupled with Hydrogen Evolution Reaction. Chin. Chem. Lett. 2024, 35, 109916. (Editorial)
34.T.-Y. Gao, X.-Y. Mo, S.-R. Zhang, Y.-X. Jiang, S.-P. Luo, J.-H. Ye,* D.-G. Yu*, Visible-light photoredox-catalyzed carboxylation of aryl epoxides with CO2. Chin. Chem. Lett. 2024, 35, 109364.
35.Y. Liu,† Z.-H. Wang,† L. Yuan , Y. Li, D.-G. Yu, J.-H. Ye*, Photocatalytic Dicarboxylation of Strained C–C Bonds with CO2 via Consecutive Visible-Light-Induced Electron Transfer. Chin. Chem. Lett. 2024, 35, 109138 († Equal contribution)
36.贵永远, 陈小旺, 余达刚*，铜催化二氧化碳参与的芳基烯烃不对称硼羧化反应。有机化学，2024，44，1038-1040 (亮点评述)
37.G.-Q. Sun,† P. Yu,† W. Zhang,† W. Zhang, Y. Wang, L.-L. Liao, Z. Zhang, L. Li, Z. Lu, D.-G. Yu*, S. Lin* Electrochemical reactor dictates site selectivity in N-heteroarene carboxylations. Nature 2023, 615, 67 († Equal contribution. Highlighted by 中国网、基金委、ScienceDaily, EurekAlert, Chem, Chem. Syn., Chin. Sci. Bull., Chin. Chem. Lett.、X-MOL、化学加、能源学报、四川大学主页)
38.J.-P. Yue, J.-C. Xu, H.-T. Luo, X.-W. Chen, H.-X. Song, Y. Deng, L. Yuan, J.-H. Ye*, D.-G. Yu*, Metallaphotoredox-enabled aminocarboxylation of alkenes with CO2. Nat. Catal. 2023, 6, 959–968.（Highlighted by Sci. China Chem.、Synfacts 2024, 20, 0058、研之成理、催化+、化学加、今日新材料、四川大学主页）.
39.W. Zhang, D.-G. Yu*, J.-H. Ye*, Photocatalytic Activation of Water: An Unique Way to Mimic Free Hydrogen Atom for Efficient Hydrogenation. Chem 2023, 9, 2375-2377 (Highlight)
40.W. Zhang, Z. Chen, Y.-X. Jiang, L.-L. Liao, W. Wang, J.-H. Ye*, D.-G. Yu*, Arylcarboxylation of unactivated alkenes with CO2 via visible-light photoredox catalysis. Nat. Commun. 2023, 14, 3529.
41.W. Zhang,† L.-L. Liao,† L. Li, Y. Liu, L.-F. Dai, G.-Q. Sun, C.-K. Ran, J.-H. Ye*, Y. Lan*, D.-G. Yu*, Electroreductive Dicarboxylation of Unactivated Skipped Dienes with CO2. Angew. Chem. Int. Ed. 2023, 62, e202301892. († Equal contribution)
42.L. Chen, Q. Qu, C.-K. Ran, W. Wang, W. Zhang, Y. He, L.-L. Liao, J.-H. Ye*, D.-G. Yu*, Photocatalytic Carboxylation of C−N Bonds in Cyclic Amines with CO2 by Consecutive Visible-Light-Induced Electron Transfer. Angew. Chem. Int. Ed. 2023, 62, 202217918. (Highlighted by Synfacts 2023, 19, 0527)
43.S.-Y. Min, H.-X. Song, S.-S. Yan*, R. Yuan, J.-H. Ye, B.-Q. Wang, Y.-Y. Gui*, D.-G. Yu*, Photocatalytic Defluorocarboxylation Using Formate Salts as Both Reductant and Carbon Dioxide Source. Green Chem. 2023, 25, 6194-6199.
44.H.-Z. Xiao,† B. Yu,† S.-S. Yan , W. Zhang , X.-X. Li, Y. Bao, S.-P. Luo, J.-H. Ye*, D.-G. Yu*, Photocatalytic 1,3-Dicarboxylation of Unactivated Alkenes with CO2. Chin. J. Catal. 2023, 50, 222 († Equal contribution)
45.M. Miao, L. Zhu, H. Zhao, L. Song, S.-S. Yan, L.-L. Liao, J.-H. Ye*, Y. Lan*, D.-G. Yu*, Visible-light-driven thio-carboxylation of alkynes with CO2: facile synthesis of thiochromones. Sci. China Chem. 2023, 66, 1457.
46.Y.-Y. Gui,† X.-W. Chen,† D.-G. Yu*, Teaching an old N-alkylation new tricks: from SN1 and SN2 N-alkylation to radical enantioconvergent N-alkylation. Sci. Bull. 2023, 68, 1225 († Equal contribution)
47.C.-K. Ran,† H.-Z. Xiao,† L.-L. Liao,* T. Ju, W. Zhang, D.-G. Yu*, The progress and challenges in dicarboxylation with CO2. Natl. Sci. Open 2023, 2, 20220024.
48.Q. Qu,† L. Chen,† Y. Deng, Y.-Y. Gui*, D.-G. Yu*, Visible-Light Photocatalytic Barbier-Type Reaction of Aziridines and Azetidines with Unactivated Aldehydes. Synlett 2023, 34, 1385-1390 († Equal contribution)
49.K. Ren†, R. Yuan†, Y.-Y. Gui*, X.-W. Chen, S.-Y. Min, B.-Q. Wang, D.-G. Yu*, Cu-Catalyzed Reductive Aminomethylation of 1,3-Dienes with N,O-acetals: Facile Construction of β-Chiral Amines with Quaternary Stereocenters. Org. Chem. Front. 2023, 10, 467. († Equal contribution).
50.L. Song,† W. Wang,† J.-P. Yue, Y.-X. Jiang, M.-K. Wei, H.-P. Zhang, S.-S. Yan, L.-L. Liao, D.-G. Yu*, Visible-Light Photocatalytic Di- and Hydro-Carboxylation of Unactivated Alkenes with CO2. Nat. Catal. 2022, 5, 832 († Equal contribution)
51.C.-K. Ran, D.-G. Yu*, Ready and label. Nat. Chem. Rev. 2022, 6, 679 (News & Views)
52.W.-J. Zhou, C.-K. Ran, D.-G. Yu*, 硼自由基助力苄基C-OH键羧基化。有机化学 2022, 42, 2599.
53.Z. Zhang, Y. Deng, Q.-F. Zhang*, D.-G. Yu*, 可见光促进二氧化碳参与的羧基化反应 高等学校化学学报2022, 43, 20220255.
54.Z.-Y. Bo†, S.-S. Yan†, T.-Y. Gao, L. Song, C.-K. Ran, Y. He, W. Zhang*, G.-M. Cao, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Selective Carboxylation of C(sp2)−F Bonds in Polyfluoroarenes with CO2. Chin. J. Catal. 2022, 43, 2388-2394. († Equal contribution)
55.Y. Huang,* D.-G. Yu*, G. Wang,* Preface to special column on catalytic conversion of CO2. Chin. J. Catal. 2022, 43, 1545-1546. (Editorial)
56.L.-L. Liao, L. Song, S.-S. Yan, J.-H. Ye,* D.-G. Yu*, Highly reductive photocatalytic systems in organic synthesis. Trend. Chem. 2022, 4, 512-527.
57.L.-L. Liao, Z.-H. Wang, K.-G. Cao, G.-Q. Sun, W. Zhang, C.-K. Ran, Y. Li, L. Chen, G.-M. Cao, D.-G. Yu*, Electrochemical Ring-Opening Dicarboxylation of Strained Carbon-Carbon Single Bonds with CO2: Facile Synthesis of Diacids and Derivatization into Polyesters. J. Am. Chem. Soc. 2022, 144, 2062.
58.C.-K. Ran,† Y.-N. Niu,† L. Song, M.-K. Wei, Y.-F. Cao, S.-P. Luo, Y.-M. Yu, L.-L. Liao,* D.-G. Yu*, Visible-Light Photoredox-Catalyzed Carboxylation of Activated C(sp3)─O bonds with CO2. ACS Catal. 2022, 12, 18. († Equal contribution. Top 1 of the most read articles in ACS Catal. in December 2021 )
59.K. Jing, M.-K. Wei, S.-S. Yan, L.-L. Liao, Y.-N. Niu, S.-P. Luo, B. Yu*, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Carboxylation of Benzyl Halides with CO2: Mild and Transition-Metal-Free. Chin. J. Catal. 2022, 43, 1667. (Invited contribution for "Catalytic Conversion of CO2")
60.X.-Y. Zhou, X.-Y. Li, Z. Zhang*, D.-G. Yu*, Thiocarbonylation of C(sp3)-H bonds in pyridylamines with CS2: Facile synthesis of pyrido[1,2-a]pyrimidine-4-thiones. Chin. Chem. Lett. 2021, 32, 4015..
61.G.-Q. Sun, W. Zhang, L.-L. Liao, L. Li, Z.-H. Nie, J.-G. Wu, Z. Zhang, D.-G. Yu*, Nickel-Catalyzed Electrochemical Carboxylation of Unactivated Aryl and Alkyl Halides with CO2. Nat. Commun. 2021, 12, 7086.
62.J. Liu†, H.-Z. Xiao†, Q. Fu,* D.-G. Yu*, Advances in Radical Phosphorylation from 2016 to 2021. Chem. Syn. 2021, 1, 9 († Equal contribution. Invited contribution)
63.S.-S. Yan, S.-H. Liu, L. Chen, Z.-Y. Bo, K. Jing, T.-Y. Gao, B. Yu, Y. Lan,* S.-P. Luo, D.-G. Yu*, Visible-light photoredox-catalyzed selective carboxylation of C(sp3)−F bonds with CO2. Chem 2021, 7, 3099.
64.X.-Y. Zhu,† C.-K. Ran,† M. Wen, G.-L. Guo, Y. Liu, L.-L. Liao, Y.-Z. Li,* M.-L. Li, D.-G. Yu*, Prediction of multicomponent reaction yields using machine learning. Chin. J. Chem. 2021, 39, 3231 († Equal contribution)
65.C.-K. Ran,† L.-L. Liao,† T.-Y. Gao, Y.-Y. Gui*, D.-G. Yu*, Recent progress and challenges in carboxylation with CO2. Cur. Opin. Green Sustain. Chem. 2021, 32, 100525 († Equal contribution)
66.D.-G. Yu*, L.-N. He*, Introduction to CO2 utilisation. Green Chem. 2021, 23, 3499. (Editorial)
67.J.-H. Ye, T. Ju, H. Huang, L.-L. Liao, D.-G. Yu*, Radical Carboxylative Cyclizations and Carboxylations with CO2. Acc. Chem. Res. 2021, 54, 2518.
68.T. Ju, Y.-Q. Zhou, K.-G. Cao, Q. Fu, J.-H. Ye, G.-Q. Sun, X.-F. Liu, L. Chen, L.-L. Liao, D.-G. Yu*, Dicarboxylation of alkenes, allenes, and (hetero)arenes with CO2 via visible-light photoredox catalysis. Nat. Catal. 2021, 4, 304–311.
69.G.-M. Cao, X.-L. Hu, L.-L. Liao, S.-S. Yan, L. Song, J. J. Chruma, L. Gong, D.-G. Yu*, Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2. Nat. Commun. 2021, 12, 3306
全部服务领域
余达刚博士，男，1986年9月出生于江西奉新。
学习经历
2003.09—2007.07 四川大学化学学院读本科，导师：冯小明教授，袁立华教授
2007.09—2012.07北京大学化学与分子工程学院有机化学专业攻读博士学位，导师：施章杰教授
工作经历
2012.10—2014.12 德国明斯特大学进行博士后研究，洪堡学者，导师： Prof. Frank Glorius
2015.01至今 四川大学化学学院从事教学和科研，教授, 博士生导师
学术兼职
Chem. Synth.副主编
Chin. Chem. Lett.副主编
《化学学报》、《有机化学》、Asian J. Org. Chem.编委
Sci. Bull. 和《科学通报》、Sci. China Chem.和《中国科学-化学》、Chin. J. Catal.青年编委
Tetrahedron Green Chem, Advisory Board Member
中国化学会二氧化碳化学专业委员会委员
中国化学会光化学专业委员会委员
中国化学会催化委员会均相催化专业委员会委员
中国化学会青年化学工作者委员会第三届委员
中国感光学会第一届青年理事会理事
主要研究方向
绿色有机合成化学（二氧化碳利用、可见光催化、电化学）
过渡金属催化方法学（铜、铁等廉价金属催化）
功能分子构建新方法研究（重要杂环、羧酸合成）
诚招副研究员、博后、研究助理、硕博生以及交流生
主要工作业绩
二氧化碳（CO2）作为空气中的重要组分，也是广泛存在、廉价易得、无毒、稳定、可再生循环使用的“碳一”（C1）资源。由于CO2在热力学和动力学方面有较高的稳定性，反应活性较低，CO2活化具有巨大的挑战。2015年余达刚博士独立建组以来，坚持围绕CO2活化与转化的基本科学问题开展独特研究，发展了CO2高效活化与选择性转化的新理念、新策略和新反应，具体如下：
针对碳氢键氧化羰基化反应中存在的问题（需要使用剧毒的CO和当量的氧化剂），我们首次提出“CO2 = CO + [O]”理念，利用CO2代替CO和氧化剂参与碳氢键羰基化反应，发展了近十类重要含羰基杂环类化合物的高效合成方法，提出了新反应机制，不仅变废为宝，还降低成本，提高安全性，具有较强的实用性；基于过渡金属催化和可见光催化策略，我们发展了“自由基型CO2转化”模式，一方面通过调控自由基参与不饱和烃转化反应的选择性，在室温常压下实现了噁唑啉酮和多种类型羧酸的高效制备，另一方面基于“可见光促进单电子活化”策略和电还原策略，通过单电子还原CO2或底物形成自由基负离子，实现了具有独特区域选择性的烯烃羧基化反应以及氮杂芳烃区域选择性可调控的羧基化反应；基于极性翻转策略，我们通过惰性化学键（如碳氟键、碳氮键和碳氧键）的选择性断裂实现了CO2参与的羧基化反应；此外，我们实现了铜或镍催化CO2参与的不饱和烃的碳碳成键反应，取得了优秀的对映选择性、化学选择性、区域选择性和Z/E选择性，高效构建了具有手性（季碳）中心的高苄醇、高烯丙醇和羧酸。这些工作实现了CO2的变废为宝和高附加值产品的精准合成，为研究CO2活化的本质和规律提供了新的实验基础和理论模型，为促进我国CO2化学研究起了积极的作用。
独立工作以来，余达刚博士以通讯作者身份在Nature、Nature Catal.、Nature Synth.、Acc. Chem. Res.、Chem.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Nature Commun.、Sci. Bull.、Chin. J. Catal.、CCS Chem.、Sci. China Chem.、Chin. Chem. Lett.和Chin. J. Chem.等学术刊物上发表学术论文110余篇，其中有多篇论文成为相应期刊封面、扉页文章、VIP和当月下载量前列的文章，多篇被国家自然科学基金委、科学网、中国网、ChemistryViews、Synform、Synfacts、Organic Chemistry Portal、OPR&D和《有机化学》等作为亮点介绍。此外，在国内外学术会议、大学和企业做了130余次报告，并作为共同客座编辑组织了Chin. J. Chem.、Green Chem.和Chin. J. Catal.等期刊的“二氧化碳化学”专辑。
主要奖励和荣誉
2025年度新时代青年先锋奖
2025年光化学与光催化青年科学家奖
2025年 “Chemical Society Reviews” Pioneering Investigators
2025年 “Chemical Communications” Pioneering Investigators
2025年中国青年科技工作者协会会员
2025年四川大学“优秀共产党员”
爱思唯尔 (Elsevier) 2024“中国高被引学者”
2024年第十八届中国青年科技奖
2024年四川大学“十佳”学生集体
2024年四川大学中长期“双高计划”
2023年中国化学会-英国皇家化学会青年化学奖
2023年度四川十大科学进展
爱思唯尔 (Elsevier) 2023“中国高被引学者”
2023年四川大学十大基础研究进展奖
2023年四川大学优秀本科毕业论文指导教师
2022年国家自然科学基金委杰出青年基金
2022 Kyoto Rising-Star Lectureship Award
2022年四川省学术和技术带头人
2021年中国催化新秀奖
2021年川渝科学技术大会优秀学术论文一等奖
2021年四川大学“先进个人”、四川大学百人计划A
2021年大学生创新创业教育优秀指导教师、四川大学拔尖创新人才优秀指导教师、四川大学优秀社团指导教师
2020年“Science China Chemistry” Emerging Investigator
2020年“Chemical Communications” Emerging Investigator
2020年 四川大学“中青年科技领军人才培育计划”
2019年四川大学优秀本科毕业论文指导教师、四川大学拔尖创新人才培养优秀指导教师、四川大学大学生创新创业教育优秀指导教师、四川大学课堂教学质量优秀奖
2018年中国化学会青年化学奖
2018年国家自然科学基金委优秀青年基金
2018年霍英东青年教师基金
2018年四川大学优秀教师、四川大学优秀青年科技人才奖
2017 ACP Lectureship Awards to Japan
2017 Thieme Chemistry Journal Award
2017年四川大学优秀本科毕业论文指导教师、四川大学拔尖创新人才优秀指导教师、四川大学大学生创新创业教育优秀指导教师
2016年“Organic Chemistry Frontiers” Emerging Investigator
2016年四川大学青年科技人才奖、四川大学优秀本科毕业论文指导教师
2014年海外高层次人才引进计划青年项目
2013-2014年德国洪堡奖学金
2013年Reaxys PhD Prize (Finalist)
代表性成果 （获奖成果、专著、论文、专利）
1.X.-L. Hu,† L.-L. Liao,† J.-C. Xu,† J.-W. Yang, J.-Y. Wu, S. Zhang, S.-C. Wang, J.-P. Yue, Y. Jiang, G.-M. Cao, L, Song,* J.-H. Ye, D.-G. Yu*, Visible-Light-Driven α-C(sp3)−H Carboxylation of Primary Benzylamines with CO2 to Access α-Amino Acids. Angew. Chem. Int. Ed. 2025, 64, e202515737. († Equal contribution. Highlighted by化学深耕堂、雁城方法学、研之成理、X-Mol、CBG)
2.W. Wang,† S.-S. Yan,† Y. Liu, J.-S. Zhu, J.-W. Yang, J.-C. Xu, Y.-Y. Tao, J.-C. Li, L. Song, J.-H. Ye,* D.-G. Yu*, Photocatalytic 1,2-Dicarboxylation of Unactivated Alkynes with CO2. J. Am. Chem. Soc. 2025, 147, 23715–23723. († Equal contribution. Highlighted by Synfacts 2025, 21, 918; 化学深耕堂、化学加、CBG、催化计、邃瞳科学云、微算云平台、半池清月)
3.Chao Li,† X.-W. Chen,† L.-L. Liao,† Y.-Y. Gui*, J.-W. Yang, S. Zhang, J.-P. Yue, X. Zhou*, J.-H. Ye, Y. Lan, D.-G. Yu*, Nickel-Catalyzed Atroposelective Carbo-Carboxylation of Alkynes with CO2: En Route to Axially Chiral Carboxylic Acids. Angew. Chem. Int. Ed. 2025, 64, e202413305. († Equal contribution. Hot Paper. Highlighted by化学深耕堂、X-Mol、CBG、有机文献速览、微算云平台)
4.J.-C. Xu,† J.-P. Yue,† M. Pan, Y.-C. Chen, W. Wang, X. Zhou, W. Zhang*, J.-H. Ye, D.-G. Yu*, Metallaphotoredox-catalyzed alkynylcarboxylation of alkenes with CO2 and alkynes for expedient access to β-alkynyl acids. Nat. Commun. 2025, 16, 1850. († Equal contribution. Highlighted by Synfacts 2025, 21, 594;有机文献速览、化学身边学、邃瞳科学云)
5.G.-M. Cao,† S.-S. Yan,† L. Song,* Y.-X. Jiang, T.-Y Gao, Z. Chen, W. Zhang,* J.-H. Ye, D.-G. Yu*, Navigating the functionalization of unactivated alkenes via visible-light photocatalysis. Chem. Soc. Rev. 2025, 54, 6726–6806. († Equal contribution.)
6.H.-Y. Huang, M. Xie, S.-Q. Wang, Y.-T. Huang, Y.-H. Luo, D.-G. Yu, Z.-Z. Cai*, J.-B. Zhu*, Ultratough Thermoplastic Elastomers Based on Chemically Recyclable Cycloalkyl-Substituted Polyhydroxyalkanoates. J. Am. Chem. Soc. 2025, 147, 7788.
7.X. Li, W. Yang, J.-P. Yue, J. Li*, S. Shen, R. Chen, J. Wang, H. Dan, D.-G. Yu, F. Dong*, Photocatalytic C-N coupling from stable and transient intermediates for gram-scale acetamide synthesis. Nat. Commun. 2025, 16, 3590.
8.H. Zhao,† Y.-C. Chen,† X.-T. Li, D.-W. Sun, L. Ye, J.-B. Zhu, J.-H. Ye, X.-H. Xiong,* Z.-S. Wu, D.-G. Yu*, Electroreductive Carboxylation of Graphite with CO2 for Lithium-Sulfur Battery with Boosting Performance. Chem. Commun. 2025, 61, 15838–15841. († Equal contribution. ChemComm Pioneering Investigators themed collection)
9.J.-W. Yang,† C.-K. Ran,† W.-J. Zhu, Y. Jiang, S.-S. Yan,* J.-H. Ye, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Carboxylation of Benzylic C(sp3)─O Bonds in Ethers with CO2. J. Org. Chem. 2025, 90, 8406–8412. († Equal contribution.)
10.Q. Zhou, C. Zhang, H.-L. Luo, C.-X. Nie, C. Hu, J.-H. Ye, Z. Su*, L.-L. Liao*, D.-G. Yu*, Carbon–metal bond homolysis-recombination enabling enantioconvergent carboxylation with CO2: A theoretical study. Chin. Chem. Lett. 2025, 36, 111429.
11.Y.-Y. Jiang,† Z. Chen,† Y.-X. Jiang, W.-J. Zhu, J.-C. Xu, J.-H. Ye, W. Zhang*, D.-G. Yu*, Visible-light-driven thiolate-catalyzed carbo-carboxylation of alkenes with CO2: facile synthesis of oxindole-3-acetic acids derivatives. Chin. J. Chem. 2025, 43, 2341–2346. († Equal contribution. Highlighted by CJC、CBG)
12.W.-C. Li, J. Ming,* D.-G. Yu*, Stereoselective C(sp3)–H alkylation of saturated heterocycles with olefins. Sci. China Chem. 2025, 68, 3912–3914. (Highlight)
13.Z. Guan,† L.-L. Liao,† Y.-Y. Gui, C. Zhang, X. Zhou, D.-G. Yu*, H. Xiang*, A Computer-Based Exercise on Racemization Mechanism and Energy Barrier of Axially Chiral Molecules. J. Chem. Educ. 2025, 102, 2398–2407.
14.L.-F. Dai,† Y.-X. Jiang,† D.-L. Yu, G.-Q. Sun, S.-S. Yan,* W. Zhang, J.-H. Ye, D.-G. Yu*, Photocatalytic Sequential Dimerization and Skeletal Rearrangement of Quinolines: Facile Synthesis of Indole-methylquinoline Hybrids. ACS Catal. 2025, 15, 7792−7799. († Equal contribution. Highlighted by化学深耕堂、CBG、研之成理、科研云资讯、科研留声机)
15.C. Li,† W. Zhang,† Y. Xu, Y. Su, T.-Y. Gao, J.-H. Ye, L. Song,* D.-G. Yu*, Carboxylation of C(sp2)−H bonds in quinolone derivatives with CO2: facile synthesis of quinolone carboxylic acids. Org. Chem. Front. 2025, 12, 4499–4505. († Equal contribution.)
16.Y.-X. Jiang, L.-L. Liao, J.-H. Ye*, D.-G. Yu*, Visible-Light-Driven Thiolate-Catalyzed Carboxylation of C(sp2)-H Bonds in Azines with CO2. Synlett 2025, 36, 1315-1321. (Invited Synpact paper)
17.Z. Zhang*, X.-L. Chen, X.-M. Xie, T.-Y. Gao, J. Qin, J.-J. Li, C. Feng, D.-G. Yu*, Iron-promoted carbonylation–rearrangement of α-aminoaryl-tethered alkylidenecyclopropanes with CO2: Facile synthesis of quinolinofurans. Chin. Chem. Lett. 2025, 36, 110056.
18.R. Ye,† J. Ming,† Q. Tao, T.-Y. Gao, J.-H. Ye, D.-G. Yu*, X. Zhou*, Transition-metal-free isofunctional reaction of α,β-unsaturated ketones/nitriles. Sci. China Chem. 2025, 68, 499-504. († Equal contribution. Highlighted by化学深耕堂、SCC)
19.G.-Q. Sun, L.-L. Liao, C.-K. Ran, J.-H. Ye, D.-G. Yu*, Recent Advances in Electrochemical Carboxylation with CO2. Acc. Chem. Res. 2024, 57, 2728-2745.(内封面，当月下载量前3)
20.J. Liu,† W. Wang,† L.-L. Liao,† W. Zhang, J.-P. Yue, Y. Liu, X.-W. Chen, J.-H. Ye*, D.-G. Yu*, Photo-Induced Carboxylation of C(sp2)−S Bonds in Aryl Thiols and Derivatives with CO2. Nat. Commun. 2024, 15, 10132. († Equal contribution. Highlighted by化学深耕堂、有趣的化学合成、化学加、CBG)
21.Y. Liu, G.-H. Xue, Z. He, J.-P. Yue, M. Pan, L. Song*, W. Zhang, J.-H. Ye, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Direct Carboxylation of Tertiary C(sp3)–H Bonds with CO2: Facile Synthesis of All-Carbon Quaternary Carboxylic Acids. J. Am. Chem. Soc. 2024, 146, 28350-28359. (当月下载量前13. Highlighted by Synfacts、化学深耕堂、X-Mol、CBG、催化计、催化开天地、催化加易点、岳麓化学、八桂化学、有机文献速览、微算云平台)
22.Q. Hu, B. Wei, M. Wang, M. Liu, X.-W. Chen, C.-K. Ran, G. Wang, Z. Chen, H. Li, J. Song, D.-G. Yu*, C. Guo*, Enantioselective nickel-electrocatalyzed reductive propargylic carboxylation with CO2. J. Am. Chem. Soc. 2024, 146, 14864–14874 (Highlighted by化学深耕堂、X-Mol、eChemStore)
23.X.-W. Chen, C. Li, Y.-Y. Gui,* J.-P. Yue, Q. Zhou, L.-L. Liao, J.-W. Yang, J.-H. Ye, D.-G. Yu*, Atropisomeric Carboxylic Acids Synthesis via Nickel-Catalyzed Enantioconvergent Carboxylation of Aza-biaryl Triflates with CO2. Angew. Chem. Int. Ed. 2024, 63, e202403401. (Highlighted by X-Mol、化学深耕堂、能源技术情报、科研留声机、CRS化学资讯、光电材料与器件)
24.Y.-Y. Gui,*,† X.-W. Chen,† X.-Y. Mo, J.-P. Yue, R. Yuan, Y. Liu, L.-L. Liao, J.-H. Ye, D.-G. Yu*, Cu-Catalyzed Asymmetric Dicarboxylation of 1,3-Dienes with CO2. J. Am. Chem. Soc. 2024, 146, 2919–2927. († Equal contribution. Highlighted by化学深耕堂、X-Mol、CBG)
25.Y.-X. Jiang,† L.-L. Liao,† T.-Y. Gao, W.-H. Xu, W. Zhang, L. Song, G.-Q. Sun, J.-H. Ye*, Y. Lan*, D.-G. Yu*, Visible-light-driven synthesis of N-heteroaromatic carboxylic acids by thiolate-catalysed carboxylation of C(sp⟡)-H bonds using CO2. Nat. Synth. 2024, 3, 394–405. († Equal contribution. Highlighted by化学加、化学深耕堂、催化计、化学宝库、有趣的化学合成、CBG)
26.B. Yu,† Y. Liu,† H.-Z. Xiao,† S.-R. Zhang, C.-K. Ran, L. Song, Y.-X. Jiang, C.-F. Li, J.-H. Ye,* D.-G. Yu*, Switchable Divergent Di- or Tricarboxylation of Allylic Alcohols with CO2. Chem 2024, 10, 938-951. (Highlighted by科学网、化学加、CBG、化学深耕堂、催化计、化学宝库、有趣的化学合成)
27.Y. Yan,† M. Pan,† J. Ming,* J.-P. Yue, X.-W. Chen, Y.-Y. Gui,* D.-G. Yu*, Transition-Metal-Catalyzed Construction of Axially Chiral Carbonyl Compounds. Eur. J. Org. Chem. 2024, 27, e202400995 († Equal contribution. Invited concept)
28.S.-R. Zhang,† J.-P. Yue,† L.-F. Wang, Y.-Y. Gui, W. Zhang,* D.-G. Yu, J.-H. Ye*, Dearomative hydroamination of heteroarenes catalyzed by the phenolate photocatalyst. Chem. Commun. 2024, 60, 13083-13086. († Equal contribution. ChemComm Emerging Investigators themed collection)
29.Y.-Y. Gui,† X.-W. Chen,† J.-P. Yue, D.-G. Yu*, Synergistic photoredox/palladium catalysis enables enantioconvergent carboxylation of racemic heterobiaryl (pseudo)halides with CO2. Chem. Synth. 2024, 4, 66. († Equal contribution. Highlight)
30.L. Li,† Z.-X. Yan,† C.-K. Ran,† Y. Liu, S. Zhang, T.-Y. Gao, L.-F. Dai, L.-L. Liao,* J.-H. Ye, D.-G. Yu*, Electro-reductive carboxylation of C─Cl bonds in unactivated alkyl chlorides and polyvinyl chloride with CO2. Chin. Chem. Lett. 2024, 35, 110104. († Equal contribution)
31.K.-G. Cao,† T.-Y. Gao,† L.-L. Liao,* C.-K. Ran, Y.-X. Jiang, W. Zhang, Q. Zhou, J.-H. Ye, Y. Lan, D.-G. Yu*, Photocatalytic carboxylation of styrenes with CO2 via C=C double bond cleavage. Chin. J. Catal. 2024, 56, 74-80. († Equal contribution)
32.C.-K. Ran, Q. Qu, Y.-Y. Tao, Y.-F. Chen, L.-L. Liao*, J.-H. Ye, D.-G. Yu*, Electro-Reductive Carboxylation of Acyclic C(sp3)─C(sp3) Bonds in Aromatic Hydrocarbons with CO2. Sci. China Chem. 2024, 67, 3366–3372.
33.X. Yao, Z. Wang*, D.-G. Yu*, Sustainable Electrosynthesis: Enantioselective Electrochemical Rh(III)/Chiral Carboxylic Acid-Catalyzed Oxidative C-H Cyclization Coupled with Hydrogen Evolution Reaction. Chin. Chem. Lett. 2024, 35, 109916. (Editorial)
34.T.-Y. Gao, X.-Y. Mo, S.-R. Zhang, Y.-X. Jiang, S.-P. Luo, J.-H. Ye,* D.-G. Yu*, Visible-light photoredox-catalyzed carboxylation of aryl epoxides with CO2. Chin. Chem. Lett. 2024, 35, 109364.
35.Y. Liu,† Z.-H. Wang,† L. Yuan , Y. Li, D.-G. Yu, J.-H. Ye*, Photocatalytic Dicarboxylation of Strained C–C Bonds with CO2 via Consecutive Visible-Light-Induced Electron Transfer. Chin. Chem. Lett. 2024, 35, 109138 († Equal contribution)
36.贵永远, 陈小旺, 余达刚*，铜催化二氧化碳参与的芳基烯烃不对称硼羧化反应。有机化学，2024，44，1038-1040 (亮点评述)
37.G.-Q. Sun,† P. Yu,† W. Zhang,† W. Zhang, Y. Wang, L.-L. Liao, Z. Zhang, L. Li, Z. Lu, D.-G. Yu*, S. Lin* Electrochemical reactor dictates site selectivity in N-heteroarene carboxylations. Nature 2023, 615, 67 († Equal contribution. Highlighted by 中国网、基金委、ScienceDaily, EurekAlert, Chem, Chem. Syn., Chin. Sci. Bull., Chin. Chem. Lett.、X-MOL、化学加、能源学报、四川大学主页)
38.J.-P. Yue, J.-C. Xu, H.-T. Luo, X.-W. Chen, H.-X. Song, Y. Deng, L. Yuan, J.-H. Ye*, D.-G. Yu*, Metallaphotoredox-enabled aminocarboxylation of alkenes with CO2. Nat. Catal. 2023, 6, 959–968.（Highlighted by Sci. China Chem.、Synfacts 2024, 20, 0058、研之成理、催化+、化学加、今日新材料、四川大学主页）.
39.W. Zhang, D.-G. Yu*, J.-H. Ye*, Photocatalytic Activation of Water: An Unique Way to Mimic Free Hydrogen Atom for Efficient Hydrogenation. Chem 2023, 9, 2375-2377 (Highlight)
40.W. Zhang, Z. Chen, Y.-X. Jiang, L.-L. Liao, W. Wang, J.-H. Ye*, D.-G. Yu*, Arylcarboxylation of unactivated alkenes with CO2 via visible-light photoredox catalysis. Nat. Commun. 2023, 14, 3529.
41.W. Zhang,† L.-L. Liao,† L. Li, Y. Liu, L.-F. Dai, G.-Q. Sun, C.-K. Ran, J.-H. Ye*, Y. Lan*, D.-G. Yu*, Electroreductive Dicarboxylation of Unactivated Skipped Dienes with CO2. Angew. Chem. Int. Ed. 2023, 62, e202301892. († Equal contribution)
42.L. Chen, Q. Qu, C.-K. Ran, W. Wang, W. Zhang, Y. He, L.-L. Liao, J.-H. Ye*, D.-G. Yu*, Photocatalytic Carboxylation of C−N Bonds in Cyclic Amines with CO2 by Consecutive Visible-Light-Induced Electron Transfer. Angew. Chem. Int. Ed. 2023, 62, 202217918. (Highlighted by Synfacts 2023, 19, 0527)
43.S.-Y. Min, H.-X. Song, S.-S. Yan*, R. Yuan, J.-H. Ye, B.-Q. Wang, Y.-Y. Gui*, D.-G. Yu*, Photocatalytic Defluorocarboxylation Using Formate Salts as Both Reductant and Carbon Dioxide Source. Green Chem. 2023, 25, 6194-6199.
44.H.-Z. Xiao,† B. Yu,† S.-S. Yan , W. Zhang , X.-X. Li, Y. Bao, S.-P. Luo, J.-H. Ye*, D.-G. Yu*, Photocatalytic 1,3-Dicarboxylation of Unactivated Alkenes with CO2. Chin. J. Catal. 2023, 50, 222 († Equal contribution)
45.M. Miao, L. Zhu, H. Zhao, L. Song, S.-S. Yan, L.-L. Liao, J.-H. Ye*, Y. Lan*, D.-G. Yu*, Visible-light-driven thio-carboxylation of alkynes with CO2: facile synthesis of thiochromones. Sci. China Chem. 2023, 66, 1457.
46.Y.-Y. Gui,† X.-W. Chen,† D.-G. Yu*, Teaching an old N-alkylation new tricks: from SN1 and SN2 N-alkylation to radical enantioconvergent N-alkylation. Sci. Bull. 2023, 68, 1225 († Equal contribution)
47.C.-K. Ran,† H.-Z. Xiao,† L.-L. Liao,* T. Ju, W. Zhang, D.-G. Yu*, The progress and challenges in dicarboxylation with CO2. Natl. Sci. Open 2023, 2, 20220024.
48.Q. Qu,† L. Chen,† Y. Deng, Y.-Y. Gui*, D.-G. Yu*, Visible-Light Photocatalytic Barbier-Type Reaction of Aziridines and Azetidines with Unactivated Aldehydes. Synlett 2023, 34, 1385-1390 († Equal contribution)
49.K. Ren†, R. Yuan†, Y.-Y. Gui*, X.-W. Chen, S.-Y. Min, B.-Q. Wang, D.-G. Yu*, Cu-Catalyzed Reductive Aminomethylation of 1,3-Dienes with N,O-acetals: Facile Construction of β-Chiral Amines with Quaternary Stereocenters. Org. Chem. Front. 2023, 10, 467. († Equal contribution).
50.L. Song,† W. Wang,† J.-P. Yue, Y.-X. Jiang, M.-K. Wei, H.-P. Zhang, S.-S. Yan, L.-L. Liao, D.-G. Yu*, Visible-Light Photocatalytic Di- and Hydro-Carboxylation of Unactivated Alkenes with CO2. Nat. Catal. 2022, 5, 832 († Equal contribution)
51.C.-K. Ran, D.-G. Yu*, Ready and label. Nat. Chem. Rev. 2022, 6, 679 (News & Views)
52.W.-J. Zhou, C.-K. Ran, D.-G. Yu*, 硼自由基助力苄基C-OH键羧基化。有机化学 2022, 42, 2599.
53.Z. Zhang, Y. Deng, Q.-F. Zhang*, D.-G. Yu*, 可见光促进二氧化碳参与的羧基化反应 高等学校化学学报2022, 43, 20220255.
54.Z.-Y. Bo†, S.-S. Yan†, T.-Y. Gao, L. Song, C.-K. Ran, Y. He, W. Zhang*, G.-M. Cao, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Selective Carboxylation of C(sp2)−F Bonds in Polyfluoroarenes with CO2. Chin. J. Catal. 2022, 43, 2388-2394. († Equal contribution)
55.Y. Huang,* D.-G. Yu*, G. Wang,* Preface to special column on catalytic conversion of CO2. Chin. J. Catal. 2022, 43, 1545-1546. (Editorial)
56.L.-L. Liao, L. Song, S.-S. Yan, J.-H. Ye,* D.-G. Yu*, Highly reductive photocatalytic systems in organic synthesis. Trend. Chem. 2022, 4, 512-527.
57.L.-L. Liao, Z.-H. Wang, K.-G. Cao, G.-Q. Sun, W. Zhang, C.-K. Ran, Y. Li, L. Chen, G.-M. Cao, D.-G. Yu*, Electrochemical Ring-Opening Dicarboxylation of Strained Carbon-Carbon Single Bonds with CO2: Facile Synthesis of Diacids and Derivatization into Polyesters. J. Am. Chem. Soc. 2022, 144, 2062.
58.C.-K. Ran,† Y.-N. Niu,† L. Song, M.-K. Wei, Y.-F. Cao, S.-P. Luo, Y.-M. Yu, L.-L. Liao,* D.-G. Yu*, Visible-Light Photoredox-Catalyzed Carboxylation of Activated C(sp3)─O bonds with CO2. ACS Catal. 2022, 12, 18. († Equal contribution. Top 1 of the most read articles in ACS Catal. in December 2021 )
59.K. Jing, M.-K. Wei, S.-S. Yan, L.-L. Liao, Y.-N. Niu, S.-P. Luo, B. Yu*, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Carboxylation of Benzyl Halides with CO2: Mild and Transition-Metal-Free. Chin. J. Catal. 2022, 43, 1667. (Invited contribution for "Catalytic Conversion of CO2")
60.X.-Y. Zhou, X.-Y. Li, Z. Zhang*, D.-G. Yu*, Thiocarbonylation of C(sp3)-H bonds in pyridylamines with CS2: Facile synthesis of pyrido[1,2-a]pyrimidine-4-thiones. Chin. Chem. Lett. 2021, 32, 4015..
61.G.-Q. Sun, W. Zhang, L.-L. Liao, L. Li, Z.-H. Nie, J.-G. Wu, Z. Zhang, D.-G. Yu*, Nickel-Catalyzed Electrochemical Carboxylation of Unactivated Aryl and Alkyl Halides with CO2. Nat. Commun. 2021, 12, 7086.
62.J. Liu†, H.-Z. Xiao†, Q. Fu,* D.-G. Yu*, Advances in Radical Phosphorylation from 2016 to 2021. Chem. Syn. 2021, 1, 9 († Equal contribution. Invited contribution)
63.S.-S. Yan, S.-H. Liu, L. Chen, Z.-Y. Bo, K. Jing, T.-Y. Gao, B. Yu, Y. Lan,* S.-P. Luo, D.-G. Yu*, Visible-light photoredox-catalyzed selective carboxylation of C(sp3)−F bonds with CO2. Chem 2021, 7, 3099.
64.X.-Y. Zhu,† C.-K. Ran,† M. Wen, G.-L. Guo, Y. Liu, L.-L. Liao, Y.-Z. Li,* M.-L. Li, D.-G. Yu*, Prediction of multicomponent reaction yields using machine learning. Chin. J. Chem. 2021, 39, 3231 († Equal contribution)
65.C.-K. Ran,† L.-L. Liao,† T.-Y. Gao, Y.-Y. Gui*, D.-G. Yu*, Recent progress and challenges in carboxylation with CO2. Cur. Opin. Green Sustain. Chem. 2021, 32, 100525 († Equal contribution)
66.D.-G. Yu*, L.-N. He*, Introduction to CO2 utilisation. Green Chem. 2021, 23, 3499. (Editorial)
67.J.-H. Ye, T. Ju, H. Huang, L.-L. Liao, D.-G. Yu*, Radical Carboxylative Cyclizations and Carboxylations with CO2. Acc. Chem. Res. 2021, 54, 2518.
68.T. Ju, Y.-Q. Zhou, K.-G. Cao, Q. Fu, J.-H. Ye, G.-Q. Sun, X.-F. Liu, L. Chen, L.-L. Liao, D.-G. Yu*, Dicarboxylation of alkenes, allenes, and (hetero)arenes with CO2 via visible-light photoredox catalysis. Nat. Catal. 2021, 4, 304–311.
69.G.-M. Cao, X.-L. Hu, L.-L. Liao, S.-S. Yan, L. Song, J. J. Chruma, L. Gong, D.-G. Yu*, Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2. Nat. Commun. 2021, 12, 3306
